85933-26-2Relevant academic research and scientific papers
The Os/Cu-Al-hydrotalcite catalysed hydroxylation of alkenes
Friedrich, Holger B.,Govender, Mayashree,Makhoba, Xolani,Ngcobo, T. Dennis,Onani, Martin O.
, p. 2922 - 2923 (2007/10/03)
A new Os/Cu-Al-hydrotalcite-like catalyst is described which, with N-methylmorpholine oxide as co-oxidant, heterogeneously catalyses the hydroxylation of olefins to give diols selectively and in high yield.
Catalytic Hydroxylation of Olefins by Polymer-Bound Osmium Tetroxide
Cainelli, Gianfranco,Contento, Michele,Manescalchi, Francesco,Plessi, Laura
, p. 45 - 47 (2007/10/02)
Osmium tetroxide, linked to insoluble crosslinked polymers and copolymers bearing tertiary amino functions, has been used in the presence of secondary oxidants, such as hydrogen peroxide, tert-butyl hydroperoxide and trimethylamine N-oxide, to accomplish the catalytic hydroxylation of olefins.The polymeric reagent offers the advantages of easy and safe handling, and simple separation from the reaction medium.Generally good yields of vicinal diols have been obtained.
