85972-34-5

Basic information

• Product Name: Ethanone, 1-[4-(phenylseleno)phenyl]-
• CAS NO: 85972-34-5
• Molecular Formula: C14H12OSe
• Molecular Weight: 275.209
• Mol File: 85972-34-5.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-(phenylseleno)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-(phenylseleno)phenyl]-(85972-34-5)
• EPA Substance Registry System: Ethanone, 1-[4-(phenylseleno)phenyl]-(85972-34-5)

Safety Data

• Hazardous Substances Data: 85972-34-5(Hazardous Substances Data)

Upstream product

• 85972-22-1 1-(3-Chloro-4-(phenylseleno)cyclohex-3-enyl)ethanone 
• 13329-40-3 4-Iodoacetophenone 
• 41924-21-4 phenyl tributylstannyl selenide 
• 1666-13-3 diphenyl diselenide 
• 99-92-3 p-aminobenzophenone 
• 85972-08-3 (E)-2-(Phenylseleno)-1,3,4-trichlorobut-2-ene 
• 85972-09-4 (E)-2-(Phenylseleno)-3-bromo-1,4-dichlorobut-2-ene 
• 34837-55-3 Phenylselenyl bromide 
• 149104-90-5 4-acetylphenylboronic acid 
• 99-90-1 para-bromoacetophenone 
• 201230-82-2 carbon monoxide 
• 645-96-5 Benzeneselenol 
• 586-89-0 4-acetyl-benzoic acid 
• 591-50-4 iodobenzene 

Downstream Products

• 182357-44-4 (RS)-1-(4-(phenylselanyl)phenyl)ethanol 

Relevant articles and documents

Palladium-Catalyzed Carbonylative Synthesis of Aryl Selenoesters Using Formic Acid as an Ex Situ CO Source

A new catalytic protocol for the synthesis of selenoesters from aryl iodides and diaryl diselenides has been developed, where formic acid was employed as an efficient, low-cost, and safe substitute for toxic and gaseous CO. This protocol presents a high functional group tolerance, providing access to a large family of selenoesters in high yields (up to 97%) while operating under mild reaction conditions, and avoids the use of selenol which is difficult to manipulate, easily oxidizes, and has a bad odor. Additionally, this method can be efficiently extended to the synthesis of thioesters with moderate-to-excellent yields, by employing for the first time diorganyl disulfides as precursors.

Forging C?S(Se) Bonds by Nickel-catalyzed Decarbonylation of Carboxylic Acid and Cleavage of Aryl Dichalcogenides

A nickel-catalyzed decarbonylation of carboxylic acids cross-coupling protocol has been developed for the straightforward C?S(Se) bond formation. This reaction is promoted by a commercially-available, user-friendly, inexpensive, air and moisture-stable nickel precatalyst. Various carboxylic acids and a wide range of aryl dichalcogenide substrates were tolerated in this process which afforded products in good to excellent yields. In addition, the present reaction can be conducted on gram scale in good yield.

Trichloroisocyanuric Acid-Promoted Synthesis of Arylselenides and Aryltellurides from Diorganyl Dichalcogenides and Arylboronic Acids at Ambient Temperature

A transition-metal-free method for the synthesis of arylselenides and aryltellurides has been established based on the oxidative cross-coupling between diorganyl dichalcogenides and aryl boronic acids. With trichloroisocyanuric acid as an oxidant, the reaction proceeded smoothly to afford the desired products in 45–97% yields at ambient temperature. Three reaction reagents used in this method are stoichiometric and the oxidation by-product isocyanuric acid can be easily isolated and recovered. Besides of arylboronic acids, aryl trifluoroborates and aryl trihydroxyborates salts are also able to perform this transformation. (Figure presented.).