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Phosphonic acid, [2,2-diphenyl-2-[(trimethylsilyl)oxy]ethyl]-, dimethyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

86000-94-4

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86000-94-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86000-94-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,0,0 and 0 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 86000-94:
(7*8)+(6*6)+(5*0)+(4*0)+(3*0)+(2*9)+(1*4)=114
114 % 10 = 4
So 86000-94-4 is a valid CAS Registry Number.

86000-94-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name dimethyl 2,2-diphenyl-2-(trimethylsiloxy)ethylphosphonate

1.2 Other means of identification

Product number -
Other names dimethyl 2,2-diphenyl-2-trimethylsiloxyethylphosphonate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:86000-94-4 SDS

86000-94-4Downstream Products

86000-94-4Relevant academic research and scientific papers

FLUORIDE ION INDUCED HORNER-EMMONS REACTION OF α-SILYLALKYLPHOSPHONATES WITH CARBONYL COMPOUNDS

Kawashima, Takayuki,Ishii, Takafumi,Inamoto, Naoki

, p. 739 - 742 (1983)

α-Trimethylsilylalkylphosphonates react with carbonyl compounds to give the corresponding olefins in the presence of fluoride ion.Use of CsF gave the best result.

Fluoride Ion-Induced Horner-Emmons Reaction of α-Silylalkylphosphonic Derivatives with Carbonyl Compounds

Kawashima, Takayuki,Ishii, Takafumi,Inamoto, Naoki

, p. 1831 - 1838 (2007/10/02)

Dimethyl α-trimethylsilylbenzylphosphonate was allowed to react with carbonyl compounds in the presence of fluoride ion to give the corresponding olefins in fairly good yields.Use of CsF in tetrahydrofuran gave the best result.On the other hand, dimethyl trimethylsilylmethylphosphonate was allowed to react similarly with benzophenone to afford 1,1-diphenylethylene, dimethyl methylphosphonate, and dimethyl 2,2-diphenylethenylphosphonate.A similar result was obtained by using O,O-diethyl trimethylsilylmethylphophonothioate.But, reaction of trimethylsilylmethylphosphonic bis(diethylamide) afforded only the protodesilylation product.

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