FLUORIDE ION INDUCED HORNER-EMMONS REACTION OF α-SILYLALKYLPHOSPHONATES WITH CARBONYL COMPOUNDS

DOI: 10.1016/S0040-4039(00)81513-0

Source and publish data:

Tetrahedron Letters p. 739 - 742 (1983)

Update date:2022-08-03

Topics:

Authors:

Kawashima, Takayuki

Ishii, Takafumi

Inamoto, Naoki

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Article abstract of DOI:10.1016/S0040-4039(00)81513-0

α-Trimethylsilylalkylphosphonates react with carbonyl compounds to give the corresponding olefins in the presence of fluoride ion.Use of CsF gave the best result.

Full text of DOI:10.1016/S0040-4039(00)81513-0

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Product name:Phosphonic acid, [2,2-diphenyl-2-[(trimethylsilyl)oxy]ethyl]-, dimethyl ester

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