860036-16-4

Usage

Uses

Used in Coordination Chemistry:
(1R,2R)-N,N'-Dihydroxy-N,N'-bis(diphenylacetyl)cyclohexane-1,2-diamine is used as a chelating agent and ligand for its ability to form stable complexes with metal ions. Its unique structure and chelating properties contribute to its effectiveness in this application.
Used in Metal Complexation Reactions:
In metal complexation reactions, (1R,2R)-N,N'-Dihydroxy-N,N'-bis(diphenylacetyl)cyclohexane-1,2-diamine serves as a key component in the synthesis of metal complexes, where its chelating ability plays a crucial role in the formation and stabilization of these complexes.
Used in Chemical Research:
(1R,2R)-N,N'-Dihydroxy-N,N'-bis(diphenylacetyl)cyclohexane-1,2-diamine is utilized in various chemical research applications due to its versatility and the potential for creating new compounds and materials through its interactions with other molecules.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, given its chelating properties and potential for complexation with metal ions, (1R,2R)-N,N'-Dihydroxy-N,N'-bis(diphenylacetyl)cyclohexane-1,2-diamine could be explored for use in the pharmaceutical industry, potentially as a component in drug design or as a tool in medicinal chemistry for targeting specific biological processes.
Used in Analytical Chemistry:
(1R,2R)-N,N'-Dihydroxy-N,N'-bis(diphenylacetyl)cyclohexane-1,2-diamine's ability to chelate metal ions could also make it useful in analytical chemistry for the development of sensors or analytical methods for detecting and quantifying metal ions in various samples.

Upstream product

• 926018-49-7 C₁₂H₂₆N₂O₂Si 
• 1871-76-7 diphenylacetic acid chloride 
• 32044-22-7 (1R,2R)-1,2-diaminocyclohexane tartrate 
• 525585-56-2 (1R,2R,N₁E,N₂E)-N₁,N₂-bis(4-methoxybenzylidene)cyclohexane-1,2-diamine 
• 860036-40-4 (R,R)-O,O'-bis(triethylsilyl)cyclohexyl-1,2-dihydroxylamine 
• 511259-84-0 (R,R)-N,N'-bis[(4-methoxyphenyl)methylene]-1,2-cyclohexanediamine 
• 860036-37-9 C₂₂H₂₆N₂O₄ 

Relevant academic research and scientific papers

Development and application of versatile bis-hydroxamic acids for catalytic asymmetric oxidation

In this article, we describe the development and preliminary results of our new designed C2-symmetric bis-hydroxamic acid (BHA) ligands and the application of the new ligands for vanadium-catalyzed asymmetric epoxidation of allylic alcohols as well as homoallylic alcohols. From this success we demonstrate the versatile nature of BHA in the molybdenum catalyzed asymmetric oxidation of unfunctionalized olefins and sulfides.

Enantioselective epoxidation of allylic alcohols by a chiral complex of vanadium: An effective controller system and a rational mechanistic model

(Chemical Equation Presented) Bishydroxamic acid derivatives are used as ligands for a vanadium catalyst in the preparation of epoxy alcohols (see scheme). The methodology uses aqueous tert-butyl hydroperoxide (TBHP) as an achiral oxidant, low catalyst loading, low reaction temperatures (0°C to room temperature), and simple workup procedures. The reaction is applied to the kinetic resolution of a secondary allylic alcohol and the preparation of small epoxy alcohols. R1, R2, R3: alkyl, aryl, H.

Catalytic asymmetric epoxidation

The present invention relates to the synthesis of chiral epoxides via a catalytic asymmetric oxidation of olefins. Additionally, the methodology provides a method of asymmetrically oxidizing sulfides and phosphines. This asymmetric oxidation employs a catalyst system composed of a metal and a chiral bishydroxamic acid ligand, which, in the presence of a stoichiometric oxidation reagent, serves to asymmetrically oxidize a variety of substrates.