86023-58-7

Basic information

• Product Name: Cyclohexanone, 2-(acetyloxy)-4-(1,1-dimethylethyl)-
• CAS NO: 86023-58-7
• Molecular Formula: C12H20O3
• Molecular Weight: 212.289
• Mol File: 86023-58-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-(acetyloxy)-4-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-(acetyloxy)-4-(1,1-dimethylethyl)-(86023-58-7)
• EPA Substance Registry System: Cyclohexanone, 2-(acetyloxy)-4-(1,1-dimethylethyl)-(86023-58-7)

Safety Data

• Hazardous Substances Data: 86023-58-7(Hazardous Substances Data)

Upstream product

• 546-67-8 lead(IV) tetraacetate 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 64-19-7 acetic acid 
• 7360-39-6 1-acetoxy-4-tert-butylcyclohexene 
• 18649-43-9 4-methoxyphenyllead(IV) triacetate 
• 16963-28-3 4-t-butyl-1-(morpholin-4-yl)cyclohex-1-ene 

Downstream Products

• 19793-88-5 trans-4-tert-Butyl-trans-2-hydroxycyclohexanol 

Relevant articles and documents

An efficient α-hydroxylation of carbonyls using the HOF·CH3CN complex

The complex HOF·CH3CN, made directly from fluorine and aqueous acetonitrile, was used for α-hydroxylation of various ketones, esters and acids via their trimethyl silyl enol ethers. The reaction is usually complete in a few minutes at room temperature or below and has high yields.

Obtention d'α-fluorocetones par oxydation anodique de derives d'enol.

To obtain fluoroketones without the use of electrophilic fluorinating reagents, we have carried out the anodic oxidation of enol esters and enol ethers in acetonitrile/Et3N, 3HF solution.With enol esters the main product is a fluoroketone or an acetoxyketone respectively, depending on the structure of the starting compound.The enol ether cation-radicals seemed to be less reactive towards H2F3- ions than the corresponding enol ester ones.