863553-44-0

Upstream product

• 122-52-1 triethyl phosphite 
• 676153-95-0 3-benzyloxy-2-benzyloxymethyl-5-iodo-2,3-dihydropyran-4-one 
• 80040-79-5 3,4,6-tri-O-benzyl-D-galactal 
• 100-39-0 benzyl bromide 
• 149561-64-8 (-)-(2R,3S)-3-(Benzyloxy)-2-<(benzyloxy)methyl>-2,3-dihydro-4H-pyran-4-one 

Downstream Products

• 1033083-22-5 C₄₆H₅₃O₁₂P 
• 1033083-32-7 methyl 3-O-acetyl-4,6-di-O-benzyl-2-deoxy-2-diethoxyphosphoryl-α-D-threo-hex-2-enopyranoside 
• 1033083-33-8 ethyl 3-O-acetyl-4,6-di-O-benzyl-2-deoxy-2-diethoxyphosphoryl-α-D-threo-hex-2-enopyranoside 
• 1033083-36-1 2'-propyl 3-O-acetyl-4,6-di-O-benzyl-2-deoxy-2-diethoxyphosphoryl-α-D-threo-hex-2-enopyranoside 
• 1033083-34-9 n-pentyl 3-O-acetyl-4,6-di-O-benzyl-2-deoxy-2-diethoxyphosphoryl-α-D-threo-hex-2-enopyranoside 
• 1033083-31-6 benzyl 3-O-acetyl-4,6-di-O-benzyl-2-deoxy-2-diethoxyphosphoryl-α-D-threo-hex-2-enopyranoside 

Relevant academic research and scientific papers

Stereoselective michael-type addition of organocopper reagents to enones derived from glycals in the synthesis of 2-phosphono-α-C-glycosides

Michael-type additions of various organocopper reagents to the novel carbohydrate-derived 2-(diethoxyphosphoryl)hex-1-en-3-uloses are described. The reactions have proved to be rapid, clean and stereoselective, giving rise to the formation of 3-oxo-2-phos