Stereoselective michael-type addition of organocopper reagents to enones derived from glycals in the synthesis of 2-phosphono-α-C-glycosides

DOI: 10.1002/ejoc.200500149

Source and publish data:

European Journal of Organic Chemistry p. 2671 - 2676 (2005)

Update date:2022-08-04

Topics:

Authors:

Leonelli, Francesca

Capuzzi, Marinella

Calcagno, Vincenzo

Passacantilli, Pietro

Piancatelli, Giovanni

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Article abstract of DOI:10.1002/ejoc.200500149

Michael-type additions of various organocopper reagents to the novel carbohydrate-derived 2-(diethoxyphosphoryl)hex-1-en-3-uloses are described. The reactions have proved to be rapid, clean and stereoselective, giving rise to the formation of 3-oxo-2-phos

Full text of DOI:10.1002/ejoc.200500149

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