86358-80-7Relevant academic research and scientific papers
Fluoro Group Pivoting Dual Hydrogen Bonding Intramolecular Bridge for 1,2-Bis(2-fluorophenyl)acenaphthenediol Molecule in Solution: NMR Spectrometrical Confirmation of Simultaneous Participation of FC(sp2) Group to Through-space-couplings with
Iitsuka, Hiroaki,Kobayashi, Miyuki,Mido, Takahiro,Noguchi, Keiichi,Okamoto, Akiko,Yonezawa, Noriyuki
supporting information, p. 295 - 298 (2020/04/10)
Dual hydrogen bonding intramolecular bridge pivoted by fluoro group for 1,2-bis(2-fluorophenyl)-3,8-dimethoxy-acenaphthenediol in solution is ascertained as simultaneous contribution of mutual fluoro group demonstrated by tangible through-space-couplings
ACYLATION OF 2,7-DIMETHOXYNAPHTHALENE
Gorelik, A. M.,Reznichenko, A. V.,Andronova, N. A.,Luk'yanets E. A.
, p. 183 - 189 (2007/10/02)
During the acylation of 2,7-dimethoxynaphthalene with acetyl chloride in the presence of boron trifluoride etherate 1-acetyl-2,7-dimethoxynaphthalene is formed.In polyphosphoric acid the main product is its 3-isomer, whereas in nitrobenzene and dichloroethane in the presence of aluminium chloride a mixture of both compounds is formed.Further acetylation of these ketones leads to 1,8- and 1,6-diacetyl-2,7-dimethoxynaphthalene respectively.The results are explained by the instability of 1-acetyl-2,7-dimethoxynaphthalene in the presence of strong protic acids.
