86475-86-7Relevant academic research and scientific papers
Structure and stereochemistry or toromycin: Studies of its acid-catalyzed rearrangement
Jain,Simolike,Jackman
, p. 599 - 605 (1983)
An antibiotic from Streptomyces has been shown to be identical with toromycin and gilvocarcin V. Toromycin has been shown by FT NOE difference spectroscopy to be a C-β-fucofuranoside and to undergo acid-catalyzed rearrangement to an approx. 1:1:2.5 mixture of toromycin and the corresponding C-α-fucofuranoside and C-β-fucopyranoside.
