Azomethine Ylide Generation via the Rhodium(II)-Induced Cyclization Reaction of Oximino α-Diazo Ketones

DOI: 10.1021/jo00289a001

Source and publish data:

Journal of Organic Chemistry p. 405 - 406 (1990)

Update date:2022-08-05

Topics:

Authors:

Padwa, Albert

Dean, Dennis C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00289a001

The rhodium(II)-catalyzed reaction of α-diazo ketones with a neighboring oxime ether generates cyclic azomethine ylides which undergo ready 1,3-dipolar cycloaddition.

Full text of DOI:10.1021/jo00289a001

Products guided by the article

Product name:Methyl 3-(5-phenyl-4,5-dihydroisoxazol-3-yl)propionate

Cas No:86492-76-4

R&D Labs maybe for 86492-76-4

Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
Jiangsu Wanlong Chemical Co., Ltd.

website:http://www.wanlongchem.com

Contact:+86-511-86810993 0086-511-8681 0888;

Address:Quanzhou Town, Danyang City, Jiangsu
Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park
Sichuan WeiKeqi Biological Technology Co., Ltd.

website:https://www.weikeqi-biotech.com/en

Contact:86-028-81700200

Address:sichuan Chengdu Qingjiang Zhonglu 63号

Relevant to this article

Mechanism of hydroboration of alkenes by dibromoborane-methyl sulfide. Remarkable catalysis of the reaction by small quantities of boron tribromide

Doi:10.1021/om50003a039
(1983)
Synthesis and antimicrobial activity of N-(substituted)-n′-[8-oxido dinaphtho-16h-2,1-z:(1′,2′-g)1,3,2-dioxaphosphocin-8-yl]ureas

Doi:10.1515/HC.2007.13.2-3.147
(2007)
Synthesis and cytotoxicity of epoxide and pyrazole analogs of the combretastatins

Doi:10.1016/j.bmc.2005.06.028
(2005)
Synthesis and physicochemical characterization of novel phenotypic probes targeting the nuclear factor-kappa B signaling pathway

Doi:10.3762/bjoc.9.103
(2013)
Synthesis of dendritic oligothiophenes and their self-association properties by intermolecular π-π interactions

Doi:10.1021/ol063046r
(2007)
Doi:10.1021/je60021a035
(1964)

Article Doi