Azomethine Ylide Generation via the Rhodium(II)-Induced Cyclization Reaction of Oximino α-Diazo Ketones

DOI: 10.1021/jo00289a001

Source and publish data:

Journal of Organic Chemistry p. 405 - 406 (1990)

Update date:2022-08-05

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Authors:

Padwa, Albert

Dean, Dennis C.

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Article abstract of DOI:10.1021/jo00289a001

The rhodium(II)-catalyzed reaction of α-diazo ketones with a neighboring oxime ether generates cyclic azomethine ylides which undergo ready 1,3-dipolar cycloaddition.

Full text of DOI:10.1021/jo00289a001

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