Azomethine Ylide Generation via the Rhodium(II)-Induced Cyclization Reaction of Oximino α-Diazo Ketones

DOI: 10.1021/jo00289a001

Source and publish data:

Journal of Organic Chemistry p. 405 - 406 (1990)

Update date:2022-08-05

Topics:

Authors:

Padwa, Albert

Dean, Dennis C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00289a001

The rhodium(II)-catalyzed reaction of α-diazo ketones with a neighboring oxime ether generates cyclic azomethine ylides which undergo ready 1,3-dipolar cycloaddition.

Full text of DOI:10.1021/jo00289a001

Products guided by the article

Product name:Methyl 3-(5-phenyl-4,5-dihydroisoxazol-3-yl)propionate

Cas No:86492-76-4

R&D Labs maybe for 86492-76-4

ABA Chemicals (Shanghai) Limited

Contact:021- 5115 9199-232

Address:Suite 18D, #201 Ningxia Road,
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District
Shandong Hongxiang Zinc Co., Ltd

Contact:086-0311-66187879

Address:DaWang developing zone
STAR SYNTHESIS CO.,LIMITED

Contact:+(852) 301-98033

Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong
SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China

Relevant to this article

Mechanism of hydroboration of alkenes by dibromoborane-methyl sulfide. Remarkable catalysis of the reaction by small quantities of boron tribromide

Doi:10.1021/om50003a039
(1983)
Synthesis and antimicrobial activity of N-(substituted)-n′-[8-oxido dinaphtho-16h-2,1-z:(1′,2′-g)1,3,2-dioxaphosphocin-8-yl]ureas

Doi:10.1515/HC.2007.13.2-3.147
(2007)
Synthesis and cytotoxicity of epoxide and pyrazole analogs of the combretastatins

Doi:10.1016/j.bmc.2005.06.028
(2005)
Synthesis and physicochemical characterization of novel phenotypic probes targeting the nuclear factor-kappa B signaling pathway

Doi:10.3762/bjoc.9.103
(2013)
Synthesis of dendritic oligothiophenes and their self-association properties by intermolecular π-π interactions

Doi:10.1021/ol063046r
(2007)
Doi:10.1021/je60021a035
(1964)

Article Doi