86504-06-5

Basic information

• Product Name: 3,5-Cyclohexadiene-1,2-diol, dibenzoate, cis-
• CAS NO: 86504-06-5
• Molecular Formula: C20H16O4
• Molecular Weight: 320.345
• Mol File: 86504-06-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,5-Cyclohexadiene-1,2-diol, dibenzoate, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Cyclohexadiene-1,2-diol, dibenzoate, cis-(86504-06-5)
• EPA Substance Registry System: 3,5-Cyclohexadiene-1,2-diol, dibenzoate, cis-(86504-06-5)

Safety Data

• Hazardous Substances Data: 86504-06-5(Hazardous Substances Data)

Upstream product

• 17793-95-2 cis-1,2-dihydrocatechol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 111015-71-5 (1α,2α,5β,6Sb)-5,6-epoxy-3-cyclohexene-1,2-diol dibenzoate 
• 111015-71-5 (1α,2α,5α,6α)-5,6-epoxy-3-cyclohexene-1,2-diol dibenzoate 
• 124647-09-2 (1L-1,2-di-O-benzoyl-4-O-methyl-chiro-inosityloxy)-(l)-menthoxyacetate 
• 124647-09-2 (1D-1,2-di-O-benzoyl-4-O-methyl-chiro-inosityloxy)-(l)-menthoxyacetate 
• 124647-08-1 <1S-(1α,2β,5β,6β)>-<5,6-di(benzoyloxy)-2-methoxy-3-cyclohexen-1-yl> (l)-menthoxyacetate 
• 124751-78-6 <1R-(1α,2β,5β,6β)>-<5,6-di(benzoyloxy)-2-methoxy-3-cyclohexen-1-yl> (l)-menthoxyacetate 
• 111015-72-6 (1α,2α,3α,6β)-6-methoxy-4-cyclohexene-1,2,3-triol 2,3-dibenzoate 
• 111015-73-7 DL-1,2-di-O-methyl-chiro-inositol 
• 111015-74-8 DL-1,3-di-O-benzoyl-4-O-methyl-chiro-inositol 
• 111015-72-6 (1α,2β,3β,6β)-6-methoxy-4-cyclohexene-1,2,3-triol 2,3-dibenzoate 
• 10284-63-6 pinitol 
• 484-68-4 4-O-methyl-myo-inositol 
• 3559-00-0 (-)-pinitol 

Relevant articles and documents

Mikrobial Oxidation in Synthesis: Preparation of (+)- and (-)-Pinitol from Benzene

Microbial oxidation with Pseudomonas putida of benzene affords cis-1,2-dihydroxycyclohexa-3,5-diene (2) which may be converted in five steps and 49percent overall yield to (+/-)-pinitol.Resolution of an intermediate alcohol (6) with menthoxyacetyl chloride provides optically pure materials which may be independently transformed to (+)- or (-)-pinitol.Demethylation conditions for pinitol together with further reactions of (2) and related compounds were investigated.