86504-11-2

Basic information

• Product Name: cis-3,5-cyclohexadiene-1,2-diol diacetate
• Synonyms: cis-3,5-cyclohexadiene-1,2-diol diacetate
• CAS NO: 86504-11-2
• Molecular Weight: 196.203
• Mol File: 86504-11-2.mol

Chemical Properties

• CAS DataBase Reference: cis-3,5-cyclohexadiene-1,2-diol diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: cis-3,5-cyclohexadiene-1,2-diol diacetate(86504-11-2)
• EPA Substance Registry System: cis-3,5-cyclohexadiene-1,2-diol diacetate(86504-11-2)

Safety Data

• Hazardous Substances Data: 86504-11-2(Hazardous Substances Data)

Upstream product

• 64288-00-2 trans-cyclohexa-3,5-diene-1,2-diyl diacetate 
• 17793-95-2 cis-1,2-dihydrocatechol 
• 108-24-7 acetic anhydride 
• 108-05-4 vinyl acetate 
• 36635-14-0 (+/-)-3c,4t,5t,6c-tetrachloro-cyclohexane-1r,2t-diol 
• 64287-99-6 trans-1,2-Diacetoxy-4,5-dibromcyclohexan 
• 17793-95-2 (1RS,2RS)-cyclohexa-3,5-diene-1,2-diol 
• 56421-33-1 3t,4c,5c,6t-tetrachloro-cyclohexane-1r,2c-diol 
• 41992-55-6 α-3,4,5,6-Tetrachlorocyclohex-1-ene 
• 64287-99-6 (1S,2,S,4S,5S)-1,2-diacetoxy-4,5-dibromocyclohexane 

Downstream Products

• 103364-68-7 (+)-(1S,2S)-1,2-dihydroxy-1,2-dihydrobenzene 
• 126874-49-5 (3aα,4α,7α,7aα,8R*,9S*)-8,9-bis(acetyloxy)-3a,4,7,7a-tetrahydro-2-phenyl-4,7-ethano-1H-isoindole-1,3(2H)-dione 
• 126814-13-9 (3aα,4α,7α,7aα,8S*,9R*)-8,9-bis(acetyloxy)-3a,4,7,7a-tetrahydro-2-phenyl-4,7-ethano-1H-isoindole-1,3(2H)-dione 
• 17793-95-2 cis-1,2-dihydrocatechol 
• 171335-61-8 (-)-(1R,2S)-1-acetoxy-2-hydroxycyclohexa-3,5-diene 
• 77804-06-9 3-(p-Chlorphenyl)-2-oxa-3-aza-bicyclo<2.2.2>-5-octen-7-endo-8-exo-diyldiacetat 
• 64288-00-2 (S,S)-1,2-diacetoxy-3,5-cyclohexadiene 
• 121073-05-0 Acetic acid (1S,6S)-6-hydroxy-cyclohexa-2,4-dienyl ester 
• 121073-05-0 Acetic acid (1R,6R)-6-hydroxy-cyclohexa-2,4-dienyl ester 
• 127877-56-9 Acetic acid (1R,2R,5S,6R)-6-acetoxy-2,5-dihydroxy-cyclohex-3-enyl ester 
• 4381-96-8 (+/-)-tetra-O-acetylconduritol F 
• 526-87-4 (+/-)-Conduritol F 
• 70134-77-9 (+)-(1S,2R,3S,6R)-7-oxabicyclo<4.1.0>hept-4-ene-2,3-diol 
• 78774-27-3 Konduramin F₁-hydrochlorid 

Relevant articles and documents

Catalytic behaviour of chloroperoxidase from Caldariomyces fumago in the oxidation of cyclic conjugated dienes

Chloroperoxidase from Caldariomyces fumago has been investigated as a catalyst for the oxidation of cyclic conjugated dienes. The nature of the substituents and the size of the carbocycle affect the enantioselectivity of the enzyme. An unexpected course o

Enzymatic Access to Homochiral 1-Acetoxy-2-hydroxycyclohexane-3,5-diene through Lipase-assisted Acetylation in Organic Solvent

Enantiotoposelective acetylation of cis-1,2-dihydroxycyclohexa-3,5-diene with vinyl acetate in tert-butyl methyl ether, promoted by immobilized lipase from Mucor miehei (Lipozyme IM), afforded (1R,2S)-1-acetoxy-2-hydroxycyclohexa-3,5-diene in good chemical yield and high enantiomeric excess.

Highly enantio- and diastereo-selective synthesis of C2-symmetric 3,5-cyclohexadiene-1,2-diol and D2-symmetric cyclohexane-1,2,4,5-tetrol

Highly enantio- and diastereo-selective synthesis of C2-symmetric 3,5-cyclohexadiene-1,2-diol 5 and D2-symmetric cyclohexane-1,2,4,5-tetrol related compounds 7a,b 10, 11 has been achieved using optically active 4-cyclohexene-1,2-diol

?-Facial diastereoselectivity in the Diels-Alder reactions of cis-cyclohexa-3,5-diene-1,2-diol and derivatives with N-phenylmaleimide

N-Phenylmaleimide undergoes Diels-Alder cycloaddition predominantly to the face of cis-cyclohexa-2,4-diene-1,2-diol (3) syn to the oxygen functions.Derivatization can be used to alter the ?-facial diastereoselectivity in a synthetically useful manner.The

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Six-membered, unsaturated carbocycles are versatile starting materials for the preparation of a large variety of modified hexoses.This is exemplified by the synthesis of N-acetylglucosamine 12 as a racemate from cis-3,5-cyclohexadiene-1,2-diol (1), which can be obtained by microbial oxidation of benzene.In this special case D- and L-N-acetylglucosamine could be differentiated by enzymatic D-galactosylation of the former. Key Words: Microbial oxidation / Epoxides / Ozonolysis / Hemiacetals / Transgalactosylation, enzymatic

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