86504-11-2Relevant articles and documents
Catalytic behaviour of chloroperoxidase from Caldariomyces fumago in the oxidation of cyclic conjugated dienes
Sanfilippo, Claudia,Nicolosi, Giovanni
, p. 1889 - 1892 (2007/10/03)
Chloroperoxidase from Caldariomyces fumago has been investigated as a catalyst for the oxidation of cyclic conjugated dienes. The nature of the substituents and the size of the carbocycle affect the enantioselectivity of the enzyme. An unexpected course o
Enzymatic Access to Homochiral 1-Acetoxy-2-hydroxycyclohexane-3,5-diene through Lipase-assisted Acetylation in Organic Solvent
Nicolosi, Giovanni,Patti, Angela,Piattelli, Mario,Sanfilippo, Claudia
, p. 6545 - 6546 (2007/10/02)
Enantiotoposelective acetylation of cis-1,2-dihydroxycyclohexa-3,5-diene with vinyl acetate in tert-butyl methyl ether, promoted by immobilized lipase from Mucor miehei (Lipozyme IM), afforded (1R,2S)-1-acetoxy-2-hydroxycyclohexa-3,5-diene in good chemical yield and high enantiomeric excess.
?-Facial diastereoselectivity in the Diels-Alder reactions of cis-cyclohexa-3,5-diene-1,2-diol and derivatives with N-phenylmaleimide
Gillard, James R.,Burnell, D. Jean
, p. 1296 - 1307 (2007/10/02)
N-Phenylmaleimide undergoes Diels-Alder cycloaddition predominantly to the face of cis-cyclohexa-2,4-diene-1,2-diol (3) syn to the oxygen functions.Derivatization can be used to alter the ?-facial diastereoselectivity in a synthetically useful manner.The