103364-68-7

Basic information

• Product Name: (1S,2S)-cyclohexa-3,5-diene-1,2-diol
• Synonyms: (1S,2S)-Cyclohexa-3,5-diene-1,2-diol; 3,5-cyclohexadiene-1,2-diol, (1S,2S)-; 3,5-Cyclohexadiene-1,2-diol, trans-(+-)-; trans-(+-)-3,5-Cyclohexadiene-1,2-diol
• CAS NO: 103364-68-7
• Molecular Formula: C₆H₈O₂
• Molecular Weight: 112.1265
• Mol File: 103364-68-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 226.4°C at 760 mmHg
• Flash Point: 109.5°C
• Density: 1.288g/cm³
• Vapor Pressure: 0.0162mmHg at 25°C
• Refractive Index: 1.607
• CAS DataBase Reference: (1S,2S)-cyclohexa-3,5-diene-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S)-cyclohexa-3,5-diene-1,2-diol(103364-68-7)
• EPA Substance Registry System: (1S,2S)-cyclohexa-3,5-diene-1,2-diol(103364-68-7)

Safety Data

• Hazardous Substances Data: 103364-68-7(Hazardous Substances Data)

Usage

General Description

(1S,2S)-cyclohexa-3,5-diene-1,2-diol is a chemical compound with the molecular formula C6H8O2. It is a diol, meaning it contains two hydroxyl (-OH) groups. (1S,2S)-cyclohexa-3,5-diene-1,2-diol is a stereochemically defined form of cyclohexa-1,2-diol, which is a cyclic diol with a six-membered ring structure. The (1S,2S) stereochemistry indicates the specific arrangement of atoms around the stereocenter at positions 1 and 2 in the cyclohexane ring. (1S,2S)-cyclohexa-3,5-diene-1,2-diol can be used as a building block in organic synthesis, and its stereochemistry can have implications for its reactivity and interactions with other molecules in chemical reactions.

Upstream product

• 64287-99-6 trans-1,2-Diacetoxy-4,5-dibromcyclohexan 
• 39078-08-5 rac-(3R,4R,5R,6R)-3,4:5,6-diepoxycyclohex-1-ene 
• 64288-00-2 trans-cyclohexa-3,5-diene-1,2-diyl diacetate 
• 1488-25-1 benzene oxide 
• 36635-14-0 (+/-)-3c,4t,5t,6c-tetrachloro-cyclohexane-1r,2t-diol 
• 64288-00-2 (S,S)-1,2-diacetoxy-3,5-cyclohexadiene 

Downstream Products

• 64330-65-0 cis,cis-2,4-hexadienedial 
• 129662-32-4 trans-1,2-Di-O-(2-methoxyethoxymethyl)cyclohexa-3,5-diene-1,2-diol 
• 35949-67-8 (1R,2S,3R,4R,5R,6S)-3,6-Bis-benzyloxy-cyclohexane-1,2,4,5-tetraol 
• 108-95-2 phenol 
• 129662-37-9 (+/-)-1,4-Di-O-benzyl-2,3,5-tri-O-(2-methoxyethoxymethyl)-chiro-inositol 
• 129662-36-8 (+/-)-1,4-Di-O-benzyl-2,3-di-O-(2-methoxyethoxymethyl)-chiro-inositol 
• 129662-35-7 (+/-)-1,2,4/3-1,4-Di-O-benzyl-2,3-O-(2-methoxyethoxymethyl)cyclohex-5-ene-1,2,3,4-tetrol 
• 129662-34-6 (+/-)-1,2,4/3-2,3-Di-O-(2-methoxyethoxymethyl)cyclohex-5-ene-1,2,3,4-tetrol 
• 526-87-4 (+/-)-Conduritol B 
• 526-87-4 conduritol A 
• 70134-77-9 (+)-(1S,2R,3S,6R)-7-oxabicyclo<4.1.0>hept-4-ene-2,3-diol 
• 20097-40-9 hexa-O-acetyl-neo-inositol 
• 4381-96-8 (+/-)-tetra-O-acetylconduritol F 
• 4381-96-8 (+/-)-tetraacetylconduritol C 

Relevant articles and documents

Highly enantio- and diastereo-selective synthesis of C2-symmetric 3,5-cyclohexadiene-1,2-diol and D2-symmetric cyclohexane-1,2,4,5-tetrol

Highly enantio- and diastereo-selective synthesis of C2-symmetric 3,5-cyclohexadiene-1,2-diol 5 and D2-symmetric cyclohexane-1,2,4,5-tetrol related compounds 7a,b 10, 11 has been achieved using optically active 4-cyclohexene-1,2-diol

Resolution of trans-1,2-Dihydroxy-1,2-dihydrobenzene for the Preparation of Optically Pure Benzene Diol Epoxides. Preparation of Bromo- and Chlorobenzene Diol Epoxides

The resolution of (+/-)-trans-1,2-dihydroxy-1,2-dihydrobenzene has been accomplished by esterase-catalysed hydrolysis of diacetate (+/-)-5.Peracid epoxidation of (+)-2 and (-)-2 gave diol epoxides (+)-3 and (-)-3, respectively.The synthesis of d