865077-50-5

Upstream product

• 75-15-0 carbon disulfide 
• 21050-95-3 N-chlorobenzotriazole 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 874-60-2 4-methyl-benzoyl chloride 
• 88-74-4 2-nitro-aniline 
• 56564-44-4 N-(2-nitrophenyl)-4-methylbenzamide 
• 71255-53-3 2'-amino-4-methylbenzanilide 
• 865073-73-0 N-(2-amino-phenyl)-4-methyl-thiobenzamide 

Downstream Products

• 79253-84-2 N,N-diethyl-4-methylthiobenzamide 
• 68055-34-5 4-methylthiobenzoic acid benzylamide 
• 16112-21-3 2-(4-methylphenyl)-1,3-benzothiazole 

Relevant academic research and scientific papers

Synthesis of 2- N / S / C -substituted benzothiazoles via intramolecular cyclative cleavage of benzotriazole ring

The synthesis of numerous 2-N/S/C-substituted benzothiazoles was achieved from substituted thiocarbonylbenzotriazoles via free-radical intramolecular cyclative cleavage of the benzotriazole ring in the presence of (TMS) 3SiH and AIBN under mild

Facile synthesis of thiazoles via an intramolecular thia-Michael strategy

A mild and efficient method for the synthesis of substituted thiazoles is reported via one-pot N-desilylation, thioacylation/oxythioacylation/thiothioacylation followed by thia-Michael cycloisomerisation. This method has a general applicability to introdu

Benzotriazole-assisted thioacylation

Benzotriazole reagents for thioacylation (RCSBt), thiocarbamoylation (RR'NCSBt), aryl/alkoxy-thioacylation (ROCSBt), and aryl/alkylthiothioacylation (RSCSBt) are synthesized, and their utility is assessed by syntheses of representative heteroaryl thioureas 3a-g, thioamides 15a-s, thionoesters 16a-h, thiocarbamates 17a-e, dithiocarbamates 18a-d, thiocarbonates 19a-c, and dithiocarbonates 20a-c.