866129-27-3Relevant academic research and scientific papers
C(sp3)-C(sp3) bond breaking in methylenecyclopropanes involving a Aui/AuIII catalytic cycle
Zhang, Di-Han,Dai, Lun-Zhi,Shi, Min
experimental part, p. 5454 - 5459 (2010/11/18)
Gold(I) can catalyze the diacetoxylation of methylenecyclopropanes to produce the corresponding diacetoxylated products in moderate to good yields in acetic acid in the presence of iodosobenzene diacetate via C-C bond breaking under mild condition.
Highly regioselective lipase-catalyzed acetylation and hydrolysis of acyclic α,α′-alkenediols and their diacetates
Hisano, Takaya,Onodera, Kotoko,Toyabe, Yasuhiro,Mase, Nobuyuki,Yoda, Hidemi,Takabe, Kunihiko
, p. 6293 - 6295 (2007/10/03)
Highly regioselective transformation of acyclic α,α′- alkenediols and their corresponding diacetates to monoacetates using lipase was accomplished. The acetylation of the α,α′-alkenediol regioselectively gave (E)-monoacetate, whereas the (Z)-monoacetate were obtained by hydrolysis of the α,α′-diacetate.
