866825-08-3

Upstream product

• 108-59-8 malonic acid dimethyl ester 
• 214978-16-2 4-(benzyloxy)but-2-ynyl methanesulfonate 
• 100-39-0 benzyl bromide 
• 91142-50-6 4-benzyloxy-2-butyn-1-ol 

Downstream Products

• 915969-13-0 2-(4-Benzyloxy-but-2-ynyl)-2-[(E)-3-((1R,2S)-2-hydroxymethyl-cyclopropyl)-but-2-enyl]-malonic acid dimethyl ester 
• 866825-13-0 ((3aS,7S)-8-(benzyloxymethyl)-7-((tert-butyldimethylsilyloxy)methyl)-2-methanesulfonyloxymethyl-4-methyl-1,2,3,3a,6,7-hexahydroazulen-2-yl)-methyl methanesulfonate 
• 866825-12-9 (3aS,7S)-dimethyl 8-((benzyloxy)methyl)-3,3a,6,7-tetrahydro-7-[(t-butyldimethylsiloxy)methyl]-4-methylazulene-2,2(1H)-dicarboxylate 
• 915969-17-4 [(3aS,7S)-8-Benzyloxymethyl-7-(tert-butyl-dimethyl-silanyloxymethyl)-2-hydroxymethyl-4-methyl-1,2,3,3a,6,7-hexahydro-azulen-2-yl]-methanol 
• 915969-16-3 (3aS,7S)-8-benzyloxymethyl-7-hydroxymethyl-4-methyl-3,3a,6,7-tetrahydro-1H-azulene-2,2-dicarboxylic acid dimethyl ester 
• 866825-11-8 (3aS,7S)-8-benzyloxymethyl-7-formyl-4-methyl-3,3a,6,7-tetrahydro-1H-azulene-2,2-dicarboxylic acid dimethyl ester 
• 866825-06-1 2-(4-benzyloxybut-2-ynyl)-2-[3-(1R,2S)-(2-formylcyclopropyl)but-2-enyl]malonic acid dimethyl ester 
• 866825-14-1 [(5S,8aS)-4-(benzyloxymethyl)-2,2,8-trimethyl-1,2,3,5,6,8a-hexahydroazulen-5-yl]methanol 
• 915969-15-2 2-(4-benzyloxy-but-2-ynyl)-2-[3-(2S,3S)-(2-carboxycyclopropyl)-but-2-enyl]malonic acid dimethyl ester 

Relevant academic research and scientific papers

Enantioselective syntheses of tremulenediol A and tremulenolide A

A concise entry to the skeleton of the tremulane sesquiterpenes is described that culminated in the first enantioselective syntheses of tremulenediol A and tremulenolide A. The approach features a series of efficient transition metal-catalyzed reactions c

Enantioselective syntheses of tremulenediol A and tremulenolide A

(Chemical Equation Presented) An enantioselective entry to the skeleton of the tremulane sesquiterpenes is described. The approach features a series of efficient transition metal-catalyzed reactions commencing with an enantioselective rhodium(II)-catalyze