866941-38-0

Upstream product

• 64979-02-8 N,N'-<(benzyloxy)carbonyl>actinamine 
• 88773-23-3 (2R,6R)-2-chloro-4-benzoyloxy-6-methyl-2H-pyran-3-(6H)-one 
• 88824-89-9 (2S,6R)-2,4-bis(benzoyloxy)-6-methyl-2H-pyran-3(6H)-one 
• 52080-34-9 1,5-anhydro-2,3,4-tri-O-benzoyl-6-deoxy-D-arabino-hex-1-enitol 

Downstream Products

• 1695-77-8 spectinomycin 
• 56733-83-6 1,3-bis(N-benzyloxycarbonyl)-spectinomycin 

Relevant academic research and scientific papers

A concise, stereocontrolled synthesis of spectinomycin

A simple and concise synthesis of the antibiotic spectinomycin is described. The key step comprises a reaction cascade initiated by the β-selective 5-O-glycosylation of an N,N-blocked myo-1,3-inosadiamine 10 with a suitable actinospectosyl donor-the d-glu

A concise and general method for doubly attaching 2-ketosugars to aglycon diols: Synthesis of the gomphosides and spectinomycin

(Chemical Equation Presented) Spectinomycin and the gomphosides: Use of 6-deoxyhexulosyl derivatives of D-glucose in Ag2CO 3-mediated glycosylation of gomphogenin and actinamine has allowed the first syntheses of cardiac glycosides with ring A-annulated sugar components (see picture; Bz = benzoyl) and an alternate synthesis of the antibiotic spectinomycin.