88773-23-3

Upstream product

• 88824-89-9 (2S,6R)-2,4-bis(benzoyloxy)-6-methyl-2H-pyran-3(6H)-one 
• 88773-24-4 1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate 
• 52080-34-9 1,5-anhydro-2,3,4-tri-O-benzoyl-6-deoxy-D-arabino-hex-1-enitol 

Downstream Products

• 88773-27-7 (4aR,6R,8aS)-8a-benzoyloxy-6-methyl-2,3,4a,8a-tetrahydro-6H-pyrano<2,3-b>-1,4-dioxin-8(7H)-one 
• 866941-37-9 C₃₆H₄₄O₉ 
• 56733-83-6 1,3-bis(N-benzyloxycarbonyl)-spectinomycin 
• 866941-38-0 2'-O-benzoyl-N,N-bis(benzyloxycarbonyl)-spectinomycin 
• 87713-55-1 cyclohexyl 3-O-benzoyl-β-D-actinospectoside 
• 88773-26-6 methyl 3-O-benzoyl-β-D-actinospectoside 

Relevant academic research and scientific papers

A concise, stereocontrolled synthesis of spectinomycin

A simple and concise synthesis of the antibiotic spectinomycin is described. The key step comprises a reaction cascade initiated by the β-selective 5-O-glycosylation of an N,N-blocked myo-1,3-inosadiamine 10 with a suitable actinospectosyl donor-the d-glu

Sugar Enolones, XIX. - An Approach to Actinospectose-Type 2,3-Diketo Sugars. - Synthetic Proof for the R Configuration of "Herzgift-Methylreduktinase"

A stereochemically defined, preparatively satisfactory access is described to stable derivatives of D-actinospectose, a 4,6-dideoxy-D-glycero-hexopyranos-2,3-diulose (3a 3b) realized in spectinomycin (1) and a series of Calotropis cardenolides (2).Key