86963-80-6Relevant articles and documents
2-CYANO Δ PIPERIDINES VIII: BIOMIMETIC APPROACH TO THE SYNTHESIS OF THE DECAHYDROQUINOLINE RING SYSTEM OF POISON-DART FROG TOXINS
Bonin, M.,Besselievre, R.,Grierson, D. S.,Husson, H.-P.
, p. 1493 - 1496 (1983)
A biomimetic approach towards the synthesis of pumiliotoxin C has been developed.The key transformation of enamine equivalent 8 to 9 was catalyzed by contact with alumina.Cyclized intermediate 9 was then reduced stereospecifically to the trans decahydroqu