Tetrahedron Letters p. 1493 - 1496 (1983)
Update date:2022-08-05
Topics:
Bonin, M.
Besselievre, R.
Grierson, D. S.
Husson, H.-P.
A biomimetic approach towards the synthesis of pumiliotoxin C has been developed.The key transformation of enamine equivalent 8 to 9 was catalyzed by contact with alumina.Cyclized intermediate 9 was then reduced stereospecifically to the trans decahydroqu
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