2-CYANO Δ PIPERIDINES VIII: BIOMIMETIC APPROACH TO THE SYNTHESIS OF THE DECAHYDROQUINOLINE RING SYSTEM OF POISON-DART FROG TOXINS

DOI: 10.1016/S0040-4039(00)81690-1

Source and publish data:

Tetrahedron Letters p. 1493 - 1496 (1983)

Update date:2022-08-05

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Authors:

Bonin, M.

Besselievre, R.

Grierson, D. S.

Husson, H.-P.

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Article abstract of DOI:10.1016/S0040-4039(00)81690-1

A biomimetic approach towards the synthesis of pumiliotoxin C has been developed.The key transformation of enamine equivalent 8 to 9 was catalyzed by contact with alumina.Cyclized intermediate 9 was then reduced stereospecifically to the trans decahydroqu

Full text of DOI:10.1016/S0040-4039(00)81690-1

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