Tetrahedron Letters p. 4505 - 4508 (1991)
Update date:2022-07-29
Topics:
Suzuki, Toshio
Sato, Ohki
Hirama, Masahiro
Yamamoto, Yoshinori
Murata, Michio
Yasumoto, Takeshi
Harada, Nobuyuki
The AB ring framework of gambiertoxin 4B which has a butadienyl substituent on the tetrahydrooxepin ring A has been synthesized stereoselectively and its CD spectrum suggests that gambiertoxin 4B and ciguatoxin have 5R configuration.
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