Enantioselective synthesis of the AB ring fragment of gambiertoxin 4B. Implication for the absolute configuration of gambiertoxin 4B and ciguatoxin

DOI: 10.1016/0040-4039(91)80025-2

Source and publish data:

Tetrahedron Letters p. 4505 - 4508 (1991)

Update date:2022-07-29

Topics:

Authors:

Suzuki, Toshio

Sato, Ohki

Hirama, Masahiro

Yamamoto, Yoshinori

Murata, Michio

Yasumoto, Takeshi

Harada, Nobuyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80025-2

The AB ring framework of gambiertoxin 4B which has a butadienyl substituent on the tetrahydrooxepin ring A has been synthesized stereoselectively and its CD spectrum suggests that gambiertoxin 4B and ciguatoxin have 5R configuration.

Full text of DOI:10.1016/0040-4039(91)80025-2

Products guided by the article

Product name:{3-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-oxiranyl}-methanol

Cas No:86990-96-7

R&D Labs maybe for 86990-96-7

SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Changzhou Jiana Chemical Co.,Ltd

website:http://www.jianachem.com

Contact:86-0519-88731808

Address:Zhenglu Town Wujin City, Jiangsu Province
Huangshan Honghui Pharm Technology Co., Ltd.(expird)

website:http://www.honghuichem.com

Contact:18855958372

Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Hangzhou Zyter Biological & Chemical Technology Co., Ltd.

website:http://www.zyterpharm.com

Contact:+86-18858184290

Address:West Wenyi Road, Cangqian, Yuhang
Chengdu Pukang Biotechnology Co., Ltd

website:http://www.pu-kang.com

Contact:86-028-63976226

Address:No. 868 Xiwang Road,Xinjin county,Chengdu city, China

Relevant to this article

Cysteine-derived organocatalyst in a highly enantioselective intramolecular Michael reaction

Doi:10.1021/ja055740s
(2005)
IPSO SUBSTITUTION OF HETEROCYCLIC TRIMETHYLSILYL CARBOXYLATES BY CARBON ELECTROPHILES

Doi:10.1016/S0040-4020(01)85961-5
(1988)
Discovery, synthesis, and structure-activity relations of 3,4-dihydro-1H-spiro(naphthalene-2,2′-piperidin)-1-ones as potassium-competitive acid blockers

Doi:10.1016/j.bmc.2017.05.012
(2017)
A heterogeneous gold(I)-catalyzed ring expansion of unactivated alkynylcyclopropanes with sulfonamides leading to (E)-2-alkylidenecyclobutanamines

Doi:10.1016/j.tetlet.2016.08.062
(2016)
Chemical lead optimization of a pan G_q mAChR M₁, M₃, M₅ positive allosteric modulator (PAM) lead. Part I: Development of the first highly selective M₅ PAM

Doi:10.1016/j.bmcl.2009.11.089
(2010)
Cassia obtusifolia MetE as a cytosolic target for potassium isolespedezate, a leaf-opening factor of cassia plants: Target exploration by a compact molecular-probe strategy

Doi:10.1002/asia.201100392
(2011)

Article Doi