Enantioselective synthesis of the AB ring fragment of gambiertoxin 4B. Implication for the absolute configuration of gambiertoxin 4B and ciguatoxin

DOI: 10.1016/0040-4039(91)80025-2

Source and publish data:

Tetrahedron Letters p. 4505 - 4508 (1991)

Update date:2022-07-29

Topics:

Authors:

Suzuki, Toshio

Sato, Ohki

Hirama, Masahiro

Yamamoto, Yoshinori

Murata, Michio

Yasumoto, Takeshi

Harada, Nobuyuki

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Article abstract of DOI:10.1016/0040-4039(91)80025-2

The AB ring framework of gambiertoxin 4B which has a butadienyl substituent on the tetrahydrooxepin ring A has been synthesized stereoselectively and its CD spectrum suggests that gambiertoxin 4B and ciguatoxin have 5R configuration.

Full text of DOI:10.1016/0040-4039(91)80025-2

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