872692-55-2Relevant academic research and scientific papers
Further studies on a samarium diiodide-promoted reductive carbon-nitrogen bond cleavage rection: Synthesis of (+)-aphanorphine
Katoh, Miho,Inoue, Hiroshi,Honda, Toshio
, p. 497 - 516 (2008/03/12)
Samarium diiodide-promoted carbon-nitrogen bond cleavage reaction was applied to the 1,2,3,4-tetrahydroisoquinoline derivatives bearing an ester group at the 1- or 3-position to give the corresponding benzazepinones. Synthesis of (+)-aphanorphine was esta
Enantioselective synthesis of (+)-aphanorphine by means of samarium diiodide promoted reductive carbon-nitrogen bond-cleavage reaction
Katoh, Miho,Inoue, Hiroshi,Suzuki, Atsuko,Honda, Toshio
, p. 2820 - 2822 (2007/10/03)
An enantioselective synthesis of (+)-aphanorphine has been achieved by application of a samarium diiodide promoted reductive carbon-nitrogen bond-cleavage reaction to a 1-methoxy-carbonyl-1,2,3,4-tetrahydroisoquinoline providing a benzazepinone derivative
