87289-85-8Relevant academic research and scientific papers
Reactions of grignard reagents with nitrous oxide
Tskhovrebov, Alexander G.,Solari, Euro,Scopelliti, Rosario,Severin, Kay
, p. 2405 - 2408 (2014)
The chemical activation of nitrous oxide (N2O) can be achieved by organocalcium, organosodium, and organolithium compounds. Grignard reagents, on the other hand, are believed to be inert. We demonstrate that this generalization is not correct. Some aliphatic Grignard reagents undergo a rapid conversion when subjected to an atmosphere of N2O. Hydrazones are the main reaction products.
Synthesis and Some Reactions of Hexahydro-1,2,4-triazine-3,6-dione
Schwan, Thomas J.
, p. 547 - 550 (2007/10/02)
The synthesis of hexahydro-1,2,4-triazine-3,6-dione by hydrogenolysis of 1,2-dibenzylhexahydro-1,2,4-triazine-3,6-dione is reported.Ring contraction of the former dione to 3-amino-2,4-imidazolininedione is discussed.The preparation of the 1- and 2-benzyl
