876-20-0

Basic information

• Product Name: 2-phenyl(~2~H_4_)ethanamine
• Synonyms: 2-Phenyl(~2~H_4_)ethanamine; benzeneethan-alpha,alpha,beta,beta-d_4_-amine
• CAS NO: 876-20-0
• Molecular Formula: C₁₀H₁₄O
• Molecular Weight: 125.2043
• Mol File: 876-20-0.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 196.5°C at 760 mmHg
• Flash Point: 90.6°C
• Density: 0.994g/cm³
• Vapor Pressure: 0.398mmHg at 25°C
• Refractive Index: 1.537
• CAS DataBase Reference: 2-phenyl(~2~H_4_)ethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenyl(~2~H_4_)ethanamine(876-20-0)
• EPA Substance Registry System: 2-phenyl(~2~H_4_)ethanamine(876-20-0)

Safety Data

• Hazardous Substances Data: 876-20-0(Hazardous Substances Data)

Upstream product

• 5896-50-4 1-(4-ethyl-2-hydroxyphenyl)-ethanone 
• 80427-50-5 1-amino-2,5-diethylbenzene 
• 34681-95-3 2-acetoxy-1,4-diethylbenzene 
• 120696-25-5 6-Ethyl-5-octen-2-yn-4-one 
• 63877-59-8 2,5-diethyl-benzenesulfonic acid 
• 105-05-5 1,4-diethylbenzene 
• 27044-40-2 6-ethyl-2,3-dimethyl-benzofuran 
• 150-76-5 4-methoxy-phenol 
• 94-71-3 2-Ethoxyphenol 
• 120-80-9 benzene-1,2-diol 
• 90-05-1 2-methoxy-phenol 
• 108-95-2 phenol 
• 123-07-9 4-Ethylphenol 
• 64-17-5 ethanol 

Downstream Products

• 253609-88-0 3-(2,6-dichloro-phenyl)-5,7a-diethyl-3a,7a-dihydro-benzo[d]isoxazole-4,7-dione 
• 6068-60-6 3-(2,5-Diethyl-phenoxy)-butan-2-on 
• 29148-37-6 2,5-diethyl-1,4-benzoquinone 

Relevant articles and documents

Guaiacol demethoxylation catalyzed by Re2O7 in ethanol

Re2O7 is used to convert guaiacol in alcohols at 280–320 °C. In ethanol, guaiacol is deoxygenated and alkylated, and the major products are phenol and alkylphenols (including ethylphenol, diethylphenol, diisopropylphenol, di-tert-butylphenol and 2,6-di-tert-butyl-4-ethylphenol), accounting for 97 mol% of all products after 6 hour reaction at 320 °C. Both catechol and phenol are the intermediates of guaiacol demethoxylation. Among the substituents, ethyl is directly provided by ethanol while isopropyl and tert-butyl are formed by the addition of methyl to ethyl step by step. In addition, Re2O7 has negligible activity for the saturation of benzene ring so it does not cause considerable over-consumption of reductant. The actual catalyst for guaiacol demethoxylation is likely a ReIV?VI species.

Method for preparing hydrocarbyl phenol by catalytic conversion of phenolic compound in presence of molybdenum-based catalyst

The invention discloses a method for preparing hydrocarbyl phenol by catalytic conversion of a phenolic compound in the presence of a molybdenum-based catalyst. The method comprises mixing a phenoliccompound, a molybdenum-based catalyst and a reaction solvent, adding the mixture into a sealed reactor, feeding gas into the reactor, heating the mixture to 150-350 DEG C, carrying out stirring for areaction for 0.5-2h, then filtering to remove a solid catalyst and carrying out rotary evaporateion to obtain a liquid product. The phenolic compound has a wide source, a cost is low, product alkyl phenol selectivity is high, an added value is high, alcohol or an alcohol-water mixture is used as a reaction solvent, environmental friendliness is realized, pollution is avoided, any inorganic acids and alkalis are avoided in the reaction process, the common environmental pollution problems in the biomass processing technology are solved, the reaction conditions are mild, the process can be carried out at a low temperature, high-efficiency conversion of the reactants can be realized without consuming hydrogen gas and the method is suitable for large-scale industrial trial production.

Enynones in Organic Synthesis. 8. Synthesis of the Antimicrobial-Cytotoxic Agent Juncusol and Members of the Effusol Class of Phenols

Two new syntheses of phenols have been developed which have been utilized in an efficient preparation of the antimicrobial-cytotoxic agent juncusol (22) and several members of the effusol (23) class of phenols.These results complement our earlier studies with enynones of type 42 and provide for the highly efficient conversion of 42 to either methylenecyclopentenones 45 or phenols of type 47 or 54 with virtually 100percent selectivity.