87736-79-6

Basic information

• Product Name: 2,2,2-Trifluoro-1-(4-methylphenyl)-O-[(4-methylphenyl)sulfonyl]oxime ethanone
• Synonyms: 2,2,2-Trifluoro-1-(4-methylphenyl)-O-[(4-methylphenyl)sulfonyl]oxime ethanone;2,2,2-Trifluoro-1-(4-methylphenyl)-O-[(4-methylphenyl)sulfonyl]oxime ethanone;2,2,2-Trifluoro-1-(4-methylphenyl)ethanone O-[(4-Methylphenyl)sulfonyl]oxime;2,2,2-Trifluoro-1-(4-methylphenyl)ethanone O-Tosyl Oxime;4-Methyl-α,a,a-Trifluoroacetophenone Oxime Tosylate;4-Methyl-a,a,a-Trifluoroacetophenone Oxime Tosylate
• CAS NO: 87736-79-6
• Molecular Formula: C₁₆H₁₄F₃NO₃S
• Molecular Weight: 357.35
• Product Categories: Aromatics Compounds;Aromatics;Sulfur & Selenium Compounds
• Mol File: 87736-79-6.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 396.87°C at 760 mmHg
• Flash Point: 193.82°C
• Appearance: /
• Density: 1.29g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.527
• Solubility: Dichloromethane, Ethyl Acetate
• CAS DataBase Reference: 2,2,2-Trifluoro-1-(4-methylphenyl)-O-[(4-methylphenyl)sulfonyl]oxime ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-Trifluoro-1-(4-methylphenyl)-O-[(4-methylphenyl)sulfonyl]oxime ethanone(87736-79-6)
• EPA Substance Registry System: 2,2,2-Trifluoro-1-(4-methylphenyl)-O-[(4-methylphenyl)sulfonyl]oxime ethanone(87736-79-6)

Safety Data

• Hazardous Substances Data: 87736-79-6(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Uses

2,2,2-Trifluoro-1-(4-methylphenyl)ethanone O-Tosyl Oxime (cas# 87736-79-6) is a compound useful in organic synthesis.

InChI:InChI=1/C16H14F3NO3S/c1-11-3-7-13(8-4-11)15(16(17,18)19)20-23-24(21,22)14-9-5-12(2)6-10-14/h3-10H,1-2H3/b20-15-

Upstream product

• 108-88-3 toluene 
• 106-38-7 para-bromotoluene 
• 75703-25-2 2,2,2-trifluoro-1-(4-methylphenyl)-1-ethanone oxime 
• 98-59-9 p-toluenesulfonyl chloride 
• 394-59-2 2,2,2-trifluoro-1-(p-tolyl)ethanone 

Downstream Products

• 870562-44-0 3-(3-methylphenyl)-3-trifluoromethyl-3H-diazirine 
• 87736-89-8 1-<<4-<3-(trifluoromethyl)-3H-diazirin-3-yl>benzoyl>oxy>-2,5-pyrrolidinedione 
• 1400565-49-2 N,N'-([4-(2-{4-[3-(trifluoromethyl)-3H-diazirin-3-yl]benzamido}ethyl)-1,2-phenylene]bis(oxyethane-2,1-diyloxyethane-2,1-diyl))bis{4-[3-(trifluoromethyl)-3H-diazirin-3-yl]benzamide} 
• 1400565-39-0 N,N',N''-[benzene-1,3,5-triyltris(oxyethane-2,1-diyloxyethane-2,1-diyl)]tris{4-[3-(trifluoromethyl)-3H-diazirin-3-yl]benzamide} 
• 1400565-40-3 N,N',N''-(2,2',2''-(2,2',2''-(2,2',2''-(benzene-1,3,5-triyltris(oxy))tris(ethane-2,1-diyl))tris(oxy)tris(ethane-2,1-diyl))tris(oxy)tris(ethane-2,1-diyl))tris(4-(3-(trifluoromethyl)-3H-diazirin-3-yl)benzamide) 
• 1400565-50-5 N,N'-(2,2'-(2,2'-(2,2'-(4-(2-(4-(3-(trifluoromethyl)-3H-diazirin-3-yl)benzamido)ethyl)-1,2-phenylene)bis(oxy)bis(ethane-2,1-diyl))bis(oxy)bis(ethane-2,1-diyl))bis(oxy)bis(ethane-2,1-diyl))bis(4-(3-(trifluoromethyl)-3H-diazirin-3-yl)benzamide) 
• 87736-85-4 4-[3-(trifluoromethyl)-3H-diaziren-3-yl]toluene 
• 92367-11-8 3-[4'-(bromomethyl)phenyl]-3-(trifluoromethyl)-3H-diazirine 
• 882429-62-1 2-[(3R,4S,5S,8S,9S,10S,11R,13R,14S,16S)-16-Acetoxy-3,11-dihydroxy-4,8,10,14-tetramethyl-hexadecahydro-cyclopenta[a]phenanthren-(17Z)-ylidene]-6-[4-(3-trifluoromethyl-3H-diazirin-3-yl)-phenyl]-hexanoic acid 2,2-dimethyl-propionyloxymethyl ester 
• 882429-59-6 2-(16-acetoxy-3,11-dihydroxy-4,8,10,14-tetramethyl-hexadecahydro-cyclopenta[a]phenanthren-17-ylidene)-6-[4-(3-trifluoromethyl-3H-diazirin-3-yl)-phenyl]-hex-5-enoic acid 2,2-dimethyl-propionyloxymethyl ester 
• 85559-46-2 4-[3-(trifluoromethyl)-3H-diazirin-3-yl]benzoic acid 
• 87736-82-1 3-(4-methylphenyl)-3-trifluoromethyldiaziridine 

Relevant articles and documents

Photochemical Cyclopropenation of Alkynes with Diazirines as Carbene Precursors in Continuous Flow

An efficient synthesis of 3-trifluoromethyl-3-aryl-cyclopropenes via the cyclopropenation reaction of alkynes with photolytically generated carbenes from diazirine compounds is described. This reaction is performed in continuous flow using readily available LEDs under mild reaction conditions. This new and efficient method describes the synthesis of 25 examples of 3-trifluoromethyl-3-aryl-cyclopropenes with yields up to 97%, achieved in continuous flow with a 5 min residence time. Control experiments highlighted that diazirines are more efficient than diazo compounds for this transformation.

Rapid Mapping of Protein Interactions Using Tag-Transfer Photocrosslinkers

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Is Magnetic Bistability of Carbenes a General Phenomenon? Isolation of Simple Aryl(trifluoromethyl)carbenes in Both Their Singlet and Triplet States

p-Tolyl(trifluoromethyl)carbene and the related fluorenyl(trifluoromethyl)carbene were synthesized in solid argon and characterized by IR, UV-vis, and electron paramagnetic resonance spectroscopy as well as by quantum mechanical calculations. The carbenes