878006-97-4Relevant academic research and scientific papers
Total Synthesis and Structural Assignment of (?)-Fusaequisin A
Schmidt, Ann-Christin,Hiersemann, Martin
, (2021/12/14)
(?)-Fusaequisin A is an irregularly assembled polyketide isolated from the ascomycete Fusarium equiseti. Fusaequisin A shares a carbon backbone with curvicollide C from the ascomycete Podospora curvicolla but its absolute configuration remained hitherto u
Enantioselective synthesis of the C8-C20 segment of curvicollide C
Koerner, Marleen,Hiersemann, Martin
, p. 4979 - 4982 (2008/03/28)
The enantioselective synthesis of the C8-C20 fragment of curvicollide C has been accomplished. A catalytic asymmetric Claisen rearrangement (CAC), a diastereoselective methyl cupration of an alkynoate, and a Julia-Kocienski olefination served as key C/C-connecting transformations.
The catalytic asymmetric Claisen rearrangement (CAC) in natural product synthesis: Synthetic studies toward curvicollides A-C
K?rner, Marleen,Hiersemann, Martin
, p. 121 - 123 (2007/10/03)
A catalytic asymmetric Claisen rearrangement has been utilized as key C-C connecting transformation for the synthesis of a building block in the projected total synthesis of the fungicidal polyketides curvicollide A-C. Georg Thieme Verlag Stuttgart.
