878006-92-9Relevant academic research and scientific papers
Total Synthesis and Structural Assignment of (?)-Fusaequisin A
Schmidt, Ann-Christin,Hiersemann, Martin
, (2021/12/14)
(?)-Fusaequisin A is an irregularly assembled polyketide isolated from the ascomycete Fusarium equiseti. Fusaequisin A shares a carbon backbone with curvicollide C from the ascomycete Podospora curvicolla but its absolute configuration remained hitherto u
Catalytic asymmetric claisen rearrangement of gosteli-type allyl vinyl ethers: Total synthesis of (-)-9,10-dihydroecklonialactone B
Becker, Julia,Butt, Lena,Von Kiedrowski, Valeska,Mischler, Elisabeth,Quentin, Florian,Hiersemann, Martin
, p. 3040 - 3051 (2014/05/06)
The enantioselective synthesis of (-)-9,10-dihydroecklonialactone B is described. The catalytic asymmetric Claisen rearrangement of a Gosteli-type allyl vinyl ether was utilized to afford an acyclic α-keto ester building block endowed with functionality a
Enantioselective synthesis of the C8-C20 segment of curvicollide C
Koerner, Marleen,Hiersemann, Martin
, p. 4979 - 4982 (2008/03/28)
The enantioselective synthesis of the C8-C20 fragment of curvicollide C has been accomplished. A catalytic asymmetric Claisen rearrangement (CAC), a diastereoselective methyl cupration of an alkynoate, and a Julia-Kocienski olefination served as key C/C-connecting transformations.
