878626-72-3Relevant articles and documents
Total synthesis of apratoxin A and B using Matteson's homologation approach
Andler, Oliver,Kazmaier, Uli
, p. 4866 - 4870 (2021/06/16)
Apratoxin A and B, two members of an interesting class of marine cyclodepsipeptides are synthesized in a straightforward mannerviaMatteson homologation. Starting from a chiral boronic ester, the polyketide fragment of the apratoxins was obtainedviafive su
Total synthesis of apratoxin A
Doi, Takayuki,Numajiri, Yoshitaka,Munakata, Asami,Takahashi, Takashi
, p. 531 - 534 (2007/10/03)
We have achieved a total synthesis of apratoxin A in which thiazoline formation was accomplished from the moCys containing amide 4 using PPh 3(O)/Tf2O. Deprotection of the Troc and allyl ester in 17, coupling with tripeptide 3, and d