87874-55-3Relevant academic research and scientific papers
Electrophilic reactions of carboyl compounds and derivatives thereof: XIII preparation of bifunctional compounds from aldehydes and olefins by acylation under acidic catalysis
Luk'yanov,Koblik,Murad'yan
, p. 1593 - 1599 (2007/10/03)
The reactions of aldehydes and their O-acylated derivatives (α-chloroesters, acylals) with olefins and α-ethoxystyrene in the presence of SnCl4 and ZnCl2 were investigated. The reactions afforded various bifunctional derivatives: diols, hydroxyesters, chloroesters, 1,3-ketoalcohols.
REACTION OF ACYLOXY CARBOCATIONS WITH UNSATURATED HYDROCARBONS
Luk'yanov, S. M.,Borodaev, S. V.
, p. 453 - 458 (2007/10/02)
Under the influence of antimony pentachloride α-chlorobenzyl benzoate forms an acyloxy carbocation which is stable at -90 deg C.The latter reacts with a series of unsaturated compounds (cyclohexene, 2-butene, isobutylene, trimethylethylene, the enol acylates of isobutyraldehyde) to form 1,3-dioxolanium and 1,3-dioxanium hexachloroantimonates.
