88151-73-9Relevant academic research and scientific papers
Application of Cyanophosphates in Organic Synthesis. Reactivity of α-Cyano-α-diethylphosphonooxy Anions
Kurihara, Takushi,Santo, Kazunori,Harusawa, Shinya,Yoneda, Ryuji
, p. 4777 - 4788 (2007/10/02)
The utility of the cyanohydrin diethylphosphates derived from aldehydes (arylaldehydes,crotonaldehyde, and cinnamaldehyde) as an acyl anion equivalent was examined.Deprotonation of cyanophosphates with n-butyllithium in the presence of tetramethylethylene
CYANOPHOSPHORYLATION OF KETONES AND ALDEHYDES USING DIETHYL PHOSPHOROCYANIDATE (DEPC)
Harusawa, Shinya,Yoneda, Ryuji,Kurihara, Takushi,Hamada, Yasumasa,Shioiri, Takayuki
, p. 2932 - 2935 (2007/10/02)
A novel one-pot and high-yield cyanophosphorylation of carbony compounds is achieved by treatment of ketones or aldehydes with diethyl phosphorocyanidate (DEPC) in the presence of a catalytic amount of lithium diisopropylamide in tetrahydrofuran.KEYWORDS
