88315-64-4Relevant articles and documents
Remote conformational responses to enantiomeric excess in carboxylate-binding dynamic foldamers
Eccles, Natasha,Le Bailly, Bryden A.F.,Della Sala, Flavio,Vitórica-Yrezábal, I?igo J.,Clayden, Jonathan,Webb, Simon J.
supporting information, p. 9331 - 9334 (2019/08/08)
A crystallographically characterised zinc(ii)-capped foldamer can sense the enantiomeric excess of scalemic carboxylate solutions, including those produced by enantioselective organocatalysis, and can relay this input signal along the foldamer body to a remote glycinamide group, which then provides an NMR spectroscopic output.
Organotextile catalysis
Lee, Ji-Woong,Mayer-Gall, Thomas,Opwis, Klaus,Song, Choong Eui,Gutmann, Jochen Stefan,List, Benjamin
, p. 1225 - 1229 (2013/09/24)
Throughout human history, textiles have been integral to daily life, but their exploration in catalysis has been rare. Herein, we show a facile and permanent immobilization of organocatalysts on the textile nylon using ultraviolet light. The catalyst and
A new structural motif for bifunctional bronsted acid/base organocatalysis
Wakchaure, Vijay N.,List, Benjamin
supporting information; experimental part, p. 4136 - 4139 (2010/08/07)
"Chemical equation presented" Naturally synthetic: Acid/base catalyst (S)-I can be used in highly enantioselective alcoholytic desymmetrizations of meso anhydrides. For example, the methanolysis of cyclobutane anhydride deriva-tive 2 gave hemiester 3 in 99:1 e.r. (see scheme). Ester 3 was used in a short enantioselective synthesis of (+ )-grandisol.