88440-83-9

Basic information

• Product Name: Benzamide, N,N-diethyl-2-(2-propenyl)-
• CAS NO: 88440-83-9
• Molecular Formula: C14H19NO
• Molecular Weight: 217.311
• Mol File: 88440-83-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzamide, N,N-diethyl-2-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N,N-diethyl-2-(2-propenyl)-(88440-83-9)
• EPA Substance Registry System: Benzamide, N,N-diethyl-2-(2-propenyl)-(88440-83-9)

Safety Data

• Hazardous Substances Data: 88440-83-9(Hazardous Substances Data)

Upstream product

• 65-85-0 benzoic acid 
• 98-88-4 benzoyl chloride 
• 35466-83-2 allyl methyl carbonate 
• 1696-17-9 N,N-diethylbenzamide 
• 76041-86-6 2-bromo-N,N-diethylbenzamide 
• 106-95-6 allyl bromide 

Downstream Products

• 134-32-7 1-amino-naphthalene 
• 17496-14-9 2,3-dihydro-2-methyl-1H-inden-1-one 
• 90-15-3 α-naphthol 
• 99618-31-2 N,N-diethyl-o-<3-(trimethylsilyl)allyl>benzamide 

Relevant articles and documents

Direct allylation of aromatic and α,β-unsaturated carboxamides under ruthenium catalysis

The ruthenium-catalyzed oxidative allylation of aromatic and α,β-unsaturated carboxamides with allylic carbonates is described. These transformations proceed readily with complete linear γ-selectivity of substituted allylic carbonates. the Partner Organisations 2014.

Selective halogen - Magnesium exchange reaction via organomagnesium ate complex

Halogen-magnesium exchange of various aryl halides is achieved with a magnesium ate complex at low temperatures. Tributylmagnesate (nBu3MgLi) induces facile iodine-magnesium exchange at -78 °C. Dibutylisopropylmagnesate (iPrnBu2MgLi) is more reactive than nBu3MgLi, and this reagent accomplishes selective bromine-magnesium exchange at -78 °C. This procedure is utilized for the preparation of various polyfunctionalized arylmagnesium species. The exchange of alkenyl halides using this method proceeds with retention of configuration of the double bond.

Ortho-metalated aromatic tertiary amides: New synthetic applications

Ortho-lithio-cuprate species derived from aromatic tertiary amides exhibited a significantly larger field of application than the lithio precursor.