884604-68-6

Upstream product

• 1498-42-6 phosphorodichloridous acid ethyl ester 
• 115156-56-4 (1R,2S,5R)-5-methyl-2-<1-methyl-1-(benzylamino)ethyl>cyclohexan-1-ol 

Downstream Products

• 735301-65-2 (2R,4aS,7R,8aR)-2,3-dibenzyl-4,4,7-trimethyloctahydrobenzo[e][1,3,2]oxazaphosphinine-2-oxide 
• 735301-70-9 (1'S,2R,4aS,7R,8aR)-3-benzyl-2-(1',2'-diphenylethyl)-4,4,7-trimethyloctahydrobenzo[e][1,3,2]oxazaphosphinine-2-oxide 
• 735301-68-5 (1'S,2R,4aS,7R,8aR)-3-(1',2'-diphenylethyl)-2-ethyl-4,4,7-trimethyloctahydrobenzo[e][1,3,2]oxazaphosphinine-2-oxide 
• 3082-58-4 (S)-1,2-diphenylethyl amine 

Relevant academic research and scientific papers

Diastereoselective alkylation of chiral perhydro 1,3,2- oxazabenzophosphorinane-2-oxides derived from (-)-8-amino menthol

Chiral oxazaphosphorinanes, derived from (-)-8-amino menthol are alkylated with good to excellent diastereoselectivities. The regioselectivity in the alkylation is dependent on the base used for deprotonation. The ethyl oxazaphosphorinanes are alkylated a

Base-dependent regio- and diastereoselective alkylation of chiral perhydro 1,3,2-oxazabenzophosphorinane-2-oxides derived from (-)-8-benzylamino menthol

The regioselectivity in the alkylation of chiral perhydro 1,3,2-benzoxazaphosphorinane-2-oxides is dependent on the base used for deprotonation. The ethyl oxazaphosphorinanes are benzylated at the nitrogen substituent after deprotonation with n-BuLi, but