735301-65-2

Upstream product

• 100-39-0 benzyl bromide 
• 884604-68-6 (4aS,7R,8aR)-3-Benzyl-2-ethoxy-4,4,7-trimethyl-octahydro-benzo[e][1,3,2]oxazaphosphinine 
• 884604-68-6 (2S,4aS,7R,8aR)-3-benzyl-2-ethoxy-4,4,7-trimethyloctahydrobenzo[e][1,3,2]oxazaphosphinine 
• 1499-19-0 benzylphosphonic dichloride 
• 115156-56-4 (1R,2S,5R)-5-methyl-2-<1-methyl-1-(benzylamino)ethyl>cyclohexan-1-ol 
• 947623-30-5 (1S,2S)-1-[(2S,4aS,7R,8aR)-3-benzyl-4,4,7-trimethyl-2-oxooctahydro-2H-1,3,2-benzoxazaphosphinin-2-yl]-4-methyl-1-phenylpentan-2-ol 

Downstream Products

• 735301-70-9 (1'S,2R,4aS,7R,8aR)-3-benzyl-2-(1',2'-diphenylethyl)-4,4,7-trimethyloctahydrobenzo[e][1,3,2]oxazaphosphinine-2-oxide 

Relevant academic research and scientific papers

Asymmetric addition of chiral 1,3,2-benzoxazaphosphinine 2-oxides to aldehydes: Diastereoselective synthesis of α-substituted β-hydroxyphosphonic acids

The addition of stabilized phosphorus anions to aldehydes leads to α-substituted β-hydroxyphosphonates. The diastereoselectivity of the process is strongly influenced by the substitution of the phosphorus atom. Whereas P-ethyl derivatives provide a mixtur

Diastereoselective alkylation of chiral perhydro 1,3,2- oxazabenzophosphorinane-2-oxides derived from (-)-8-amino menthol

Chiral oxazaphosphorinanes, derived from (-)-8-amino menthol are alkylated with good to excellent diastereoselectivities. The regioselectivity in the alkylation is dependent on the base used for deprotonation. The ethyl oxazaphosphorinanes are alkylated a

Base-dependent regio- and diastereoselective alkylation of chiral perhydro 1,3,2-oxazabenzophosphorinane-2-oxides derived from (-)-8-benzylamino menthol

The regioselectivity in the alkylation of chiral perhydro 1,3,2-benzoxazaphosphorinane-2-oxides is dependent on the base used for deprotonation. The ethyl oxazaphosphorinanes are benzylated at the nitrogen substituent after deprotonation with n-BuLi, but