88481-60-1

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 74213-65-3 (2R,3R)-3-methyl-butan-1,2,4-triol 
• 88481-58-7 (2S,3R)-3-Methyl-2-(1-methoxy-1-methylethoxy)bernsteinsaeure-diethylester 
• 88481-59-8 (2S,3S)-3-Methyl-2-(1-methoxy-1-methylethoxy)-1,4-butandiol 
• 73840-71-8 diethyl (2S,3R)-(+)-2-hydroxy-3-methylsuccinate 
• 74213-64-2 (2S,3S)-erythro-3-methylbutane-1,2,4-triol 
• 100-52-7 benzaldehyde 

Downstream Products

• 128308-30-5 Isobutyric acid (1S,2S)-3-bromo-1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2-methyl-propyl ester 
• 128308-31-6 (5R,6S)-6-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3,3,5-trimethyl-tetrahydro-pyran-2-one 
• 128308-29-2 tert-Butyl-[2-((4S,5R)-5-methyl-2-phenyl-[1,3]dioxan-4-yl)-ethoxy]-diphenyl-silane 
• 131613-86-0 2-((1R,2R)-2-Benzyloxy-1-methyl-butyl)-6-((S)-2-hydroxy-1-methyl-ethyl)-3,5-dimethyl-pyran-4-one 
• 131530-52-4 2-((1R,2R)-2-Benzyloxy-1-methyl-butyl)-6-((R)-2-hydroxy-1-methyl-ethyl)-3,5-dimethyl-pyran-4-one 
• 131530-50-2 (8R,9R)-9-Benzyloxy-4,6,8-trimethyl-undecane-3,5,7-trione 
• 131530-51-3 2-((1R,2R)-2-Benzyloxy-1-methyl-butyl)-6-ethyl-3,5-dimethyl-pyran-4-one 
• 131530-48-8 (2R,3R)-3-Benzyloxy-1-imidazol-1-yl-2-methyl-pentan-1-one 
• 108661-15-0 (2R,3R)-3-Benzyloxy-2-methyl-pentanoic acid 
• 85670-59-3 1-Benzyloxy-2-methyl-pentan-3-one 
• 131530-47-7 (4R,5S)-4-Ethyl-5-methyl-2-phenyl-[1,3]dioxane 
• 102736-45-8 (3R,4S)-3,5-benzylidenedioxy-4-methylpentanamide 
• 131530-46-6 Toluene-4-sulfonic acid (4S,5S)-5-methyl-2-phenyl-[1,3]dioxan-4-ylmethyl ester 
• 80184-02-7 (2S,3S)-4-(benzyloxy)-3-methyl-1,2-butanediol 

Relevant academic research and scientific papers

SYNTHETIC STUDY ON APLYSIATOXINS, HIGHLY INFLAMMATORY AGENTS AND TUMOR PROMOTERS. SYNTHESIS OF THE THREE OPTICALLY ACTIVE SEGMENTS

The main segments in debromoaplysiatoxin and related aplysiatoxins have been efficiently synthesized from D-glucose and L- and D-tartaric acids.

Enantiomerically Pure Building Blocks for Syntheses from Branched Malates

Isocitric acid lactone (13) and the chiral building blocks (2S,3R)-4-bromo-1,2-epoxy-3-methyl-butane (21), cis- and trans 2,3-epoxy-2-methylsuccinates (23, 24), and the singly protected (2R)-2-methyl-, -2-allyl- and -2-benzyl-1,3-propanediols (32a, b, c)