88481-67-8

Upstream product

• 88481-62-3 (2S,3R)-3-Allyl-2-(1-methoxy-1-methylethoxy)bernsteinsaeure-diethylester 
• 73828-22-5 (2S,3R)-3-Allyl-2-Hydroxybernsteinsaeure-diethylester 
• 88481-64-5 (2S,3S)-3-(2-propenyl)-1,2,4-butanetriol 
• 100-52-7 benzaldehyde 
• 100-39-0 benzyl bromide 
• 88481-65-6 (4S,5S)-5-Allyl-4-hydroxymethyl-2-phenyl-1,3-dioxan 

Relevant academic research and scientific papers

Highly stereoselective chelation-controlled allylation and deuteration of α-chiral α,α'-dialkoxy radicals

Diastereoselectivity in the radical mediated allylation and deuteration reactions of β-chiral β-alkoxy-β-bromoaldehyde dimethyl acetals and a related alkoxy bromide were remarkably enhanced when the reactions were conducted in the presence of Lewis acid (MgBr2·OEt2 for allylation; MgI2 for deuteration).

Enantiomerically Pure Building Blocks for Syntheses from Branched Malates

Isocitric acid lactone (13) and the chiral building blocks (2S,3R)-4-bromo-1,2-epoxy-3-methyl-butane (21), cis- and trans 2,3-epoxy-2-methylsuccinates (23, 24), and the singly protected (2R)-2-methyl-, -2-allyl- and -2-benzyl-1,3-propanediols (32a, b, c)