Highly stereoselective chelation-controlled allylation and deuteration of α-chiral α,α'-dialkoxy radicals

DOI: 10.1246/cl.1996.845

Source and publish data:

Chemistry Letters p. 845 - 846 (1996)

Update date:2022-08-03

Topics:

Authors:

Nagano, Hajime

Azuma, Yukiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1996.845

Diastereoselectivity in the radical mediated allylation and deuteration reactions of β-chiral β-alkoxy-β-bromoaldehyde dimethyl acetals and a related alkoxy bromide were remarkably enhanced when the reactions were conducted in the presence of Lewis acid (MgBr₂·OEt₂ for allylation; MgI₂ for deuteration).

Full text of DOI:10.1246/cl.1996.845

Products guided by the article

Product name:(2S,3S)-2-Allyl-3-benzyloxy-butane-1,4-diol

Cas No:88481-67-8

R&D Labs maybe for 88481-67-8

Tianjin Derchemist Sci-Tech Co., Ltd.

website:http://www.derchemist.com

Contact:+86-22-58627059

Address:Xinmao Science and Technology Park，Huayuan Industrial Park
QINGDAO NEW FLOURISH INTERNATIOANAL TRADE CO., LTD.

Contact:+86 532 80861829

Address:No. 1, Yinchuan East Road, 266061, Qingdao, China
HAORUI ENTERPRISES LLC

Contact:(1) 206-3550089

Address:5115 NE 8TH PL, Renton, WA 98059 USA
Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
Buffett (China) Holding Co.,Ltd

Contact:4006570891

Address:

Relevant to this article

Synthesis, characterization, biocide and toxicological activities of di-n-butyl- and diphenyl-tin^IV-salicyliden-β-amino alcohol derivatives

Doi:10.1021/ic048628o
(2005)
Imino-ene reaction of N-tosyl arylaldimines with α-methylstyrene: Application in the synthesis of important amines

Doi:10.1016/j.tetlet.2005.05.073
(2005)
Organoamino phosphonium cations as building blocks for hierarchical supramolecular assemblies

Doi:10.1021/cg101447q
(2011)
Preparation of CI-1027 glucuronide: Metabolite of a remarkable lipid-modulating agent

Doi:10.1081/SCC-200061648
(2005)
Aromatization and ring cyclization: A better understanding on the ring cyclization mechanism of 3-amino-6-hydrazino-1,2,4-triazin-5(2H)-one reacted with acetic acid in N,N-dimethylformamide

Doi:10.1002/jhet.5570420516
(2005)
Radical cation Diels-Alder cycloadditions by visible light photocatalysis

Doi:10.1021/ja2093579
(2011)

Article Doi