Highly stereoselective chelation-controlled allylation and deuteration of α-chiral α,α'-dialkoxy radicals

DOI: 10.1246/cl.1996.845

Source and publish data:

Chemistry Letters p. 845 - 846 (1996)

Update date:2022-08-03

Topics:

Authors:

Nagano, Hajime

Azuma, Yukiko

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Article abstract of DOI:10.1246/cl.1996.845

Diastereoselectivity in the radical mediated allylation and deuteration reactions of β-chiral β-alkoxy-β-bromoaldehyde dimethyl acetals and a related alkoxy bromide were remarkably enhanced when the reactions were conducted in the presence of Lewis acid (MgBr₂·OEt₂ for allylation; MgI₂ for deuteration).

Full text of DOI:10.1246/cl.1996.845

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