885318-84-3Relevant academic research and scientific papers
Synthesis of enantiopure 2-amino-1-phenyl and 2-amino-2-phenyl ethanols using enantioselective enzymatic epoxidation and regio- and diastereoselective chemical aminolysis
Sello, Guido,Orsini, Fulvia,Bernasconi, Silvana,Gennaro, Patrizia Di
, p. 372 - 376 (2006)
Several enantiopure 1,2-amino alcohols have been prepared by combining a stereoselective enzymatic epoxidation of styrenes with regio- and stereoselective chemical reactions. An interesting reactivity has been noted concerning the reaction of epoxides and NH3 under microwave activation.
Asymmetric epoxidation of alkenes catalysed by chromium binaphthyl Schiff base complex supported on MCM-41
Zhou, Xiang-Ge,Yu, Xiao-Qi,Huang, Jie-Sheng,Li, Shou-Gui,Li, Lian-Sheng,Che, Chi-Ming
, p. 1789 - 1790 (2007/10/03)
A chromium(III) binaphthyl Schiff base complex immobilised on modified MCM-41 is an effective catalyst for asymmetric epoxidation of unfunctionalised alkenes and gave significantly higher ee than the free complex.
