885500-75-4

Upstream product

• 81028-12-8 (4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde 
• 622-30-0 N-benzyl hydroxylalmine 

Downstream Products

• 173382-54-2 N-Benzyl-4-O-benzyl-1-deoxy-1-(hydroxyamino)-2,3-O-isopropylidene-1-(2-thiazolyl)-L-xylo-tetritol 
• 173522-36-6 N-Benzyl-4-O-benzyl-1-deoxy-1-(hydroxyamino)-2,3-O-isopropylidene-1-(2-thiazolyl)-L-lyxo-tetritol 
• 152390-97-1 N-Benzyl-N-[(S)-((4S,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-furan-2-yl-methyl]-hydroxylamine 
• 347163-39-7 diethyl {(1S,2R,3S)-1-[benzyl(hydroxy)amino]-4-benzyloxy-2,3-(isopropylidenedioxy)butyl}phosphonate 
• 152390-99-3 [(S)-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-furan-2-yl-methyl]-carbamic acid tert-butyl ester 
• 173522-26-4 4-O-Benzyl-1-(benzyloxycarbonylamino)-1-deoxy-2,3-O-isopropylidene-1-(2-thiazolyl)-L-lyxo-tetritol 
• 173382-31-5 4-O-Benzyl-1-(benzyloxycarbonylamino)-1-deoxy-2,3-O-isopropylidene-1-(2-thiazolyl)-L-xylo-tetritol 
• 173522-25-3 4-O-Benzyl-1-(tert-butoxycarbonylamino)-1-deoxy-2,3-O-isopropylidene-1-(2-thiazolyl)-L-xylo-tetritol 
• 173382-42-8 5-O-Benzyl-2-(tert-butoxycarbonylamino)-2-deoxy-3,4-O-isopropylidene-L-xylose 

Relevant academic research and scientific papers

Stereocontrol by diethylaluminum chloride in the addition of 2-lithiofuran and N-methyl-2-lithioimidazole to αalkoxy nitrones. Total synthesis of 5-O-carbamoylpolyoxamic acid

The addition of the title metalated heterocycles 1 to the nitrone 2 derived from D-glyceraldehyde acetonide leads to the corresponding syn-adducts as major products (ds 88-96 %) while the reaction in the presence of Et2AlCl leads to anti isomer

Stereoselective synthesis of (-)-deacetylanisomycin

A stereoselective synthesis of (-)-deacetylanisomycin has been achieved from a nitrone derived from 1-threose in 6 steps and 53.7% overall yield, The key step of the synthesis is the nucleophilic addition of a Grignard derivative with complete diastereofacial selectivity. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.