Stereocontrol by diethylaluminum chloride in the addition of 2-lithiofuran and N-methyl-2-lithioimidazole to αalkoxy nitrones. Total synthesis of 5-O-carbamoylpolyoxamic acid

DOI: 10.1016/S0040-4039(00)73939-6

Source and publish data:

Tetrahedron Letters p. 5479 - 5482 (1993)

Update date:2022-07-30

Topics:

Authors:

Dondoni, Alessandro

Franco, Santiago

Merchant, Francisco Luis

Merino, Pedro

Tejerol, Tomas

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Article abstract of DOI:10.1016/S0040-4039(00)73939-6

The addition of the title metalated heterocycles 1 to the nitrone 2 derived from D-glyceraldehyde acetonide leads to the corresponding syn-adducts as major products (ds 88-96 %) while the reaction in the presence of Et₂AlCl leads to anti isomer

Full text of DOI:10.1016/S0040-4039(00)73939-6

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