88764-11-8Relevant academic research and scientific papers
Spiro[4,4]-1,6-Nonadiene-based diphosphine oxides in lewis base catalyzed asymmetric double-aldol reactions
Zhang, Panke,Han, Zhaobin,Wang, Zheng,Ding, Kuiling
supporting information, p. 11054 - 11058 (2013/10/22)
Symmetry swap: A C2-chiral spiro diphosphine oxide (SpinPO) has been found to be highly efficient and enantioselective in the catalysis of double-aldol reactions of ketones and aldehydes to give the corresponding optically active double-aldol products, which can be readily transformed into optically active C3- and pseudo-C3-symmetric molecules. Copyright
Preparation and Synthetic Use of Trimethylsilyl Polyphosphate. A New Stereoselective Aldol-Type Reaction in the Presence of Trimethylsilyl Polyphosphate
Imamoto, Tsuneo,Matsumoto, Teruyo,Yokoyama, Hideki,Yokoyama, Masataka,Yamaguchi, Kei-ichi
, p. 1105 - 1110 (2007/10/02)
A study has been made of the preparation of a new polyphosphate reagent, trimethylsilyl polyphosphate (PPSE), and its use in organic synthesis.The reaction of phosphorus pentoxide with hexamethyldisiloxane in solvent (dichloromethane or benzene), in the s
