88773-24-4

Upstream product

• 52080-34-9 1,5-anhydro-2,3,4-tri-O-benzoyl-6-deoxy-D-arabino-hex-1-enitol 

Downstream Products

• 88824-89-9 (2S,6R)-2,4-bis(benzoyloxy)-6-methyl-2H-pyran-3(6H)-one 
• 87713-55-1 cyclohexyl 3-O-benzoyl-β-D-actinospectoside 
• 88773-27-7 (4aR,6R,8aS)-8a-benzoyloxy-6-methyl-2,3,4a,8a-tetrahydro-6H-pyrano<2,3-b>-1,4-dioxin-8(7H)-one 
• 88773-26-6 methyl 3-O-benzoyl-β-D-actinospectoside 
• 88773-23-3 (2R,6R)-2-chloro-4-benzoyloxy-6-methyl-2H-pyran-3-(6H)-one 
• 88773-28-8 (2R)-5-benzoyloxy-2-methyl-2H-pyran-4(3H)-one 
• 838-76-6 5-benzoyloxy-2-methyl-4H-pyran-4-one 

Relevant academic research and scientific papers

Sugar Enolones, XIX. - An Approach to Actinospectose-Type 2,3-Diketo Sugars. - Synthetic Proof for the R Configuration of "Herzgift-Methylreduktinase"

A stereochemically defined, preparatively satisfactory access is described to stable derivatives of D-actinospectose, a 4,6-dideoxy-D-glycero-hexopyranos-2,3-diulose (3a 3b) realized in spectinomycin (1) and a series of Calotropis cardenolides (2).Key