88953-55-3Relevant academic research and scientific papers
Coupling Reaction between Aldehydes and Non-Activated Hydrocarbons via the Reductive Radical-Polar Crossover Pathway
Yahata, Kenzo,Sakurai, Shu,Hori, Shuhei,Yoshioka, Shin,Kaneko, Yuki,Hasegawa, Kai,Akai, Shuji
supporting information, p. 1199 - 1203 (2020/02/04)
Herein, we describe the generation of an organochromium-type carbanion species from a non-activated C-H bond and its nucleophilic addition to aldehydes. The catalytic carbanion generation occurred through formal deprotonation of a non-activated C-H bond under mild conditions and did not need the prefunctionalization or anion stabilizing group. Carbon radical intermediates generated by decatungstate photocatalyst-mediated hydrogen abstraction were captured by a chromium salt with the reductive radical-polar crossover reaction to produce organochromium carbanions.
Neighbour Group Participation with Reductions and Hydride Abstractions
Moehre, H.,Kamper, Ch.
, p. 512 - 520 (2007/10/02)
The reduction of N-(2-hydroxyalkyl)lactams with diisobutylaluminium hydride and the hydride ion abstraction of the corresponding amino alcohols give under neighbour group participation the fused oxazolidines.
