89036-99-7Relevant academic research and scientific papers
DIVERGENT SYNTHESIS OF 1,3- AND 1,4-DIKETONES FROM β-METHOXY-γ-PHENYLTHIO KETONES ACCESSIBLE THROUGH NOVEL PHENYLTHIO MIGRATION REACTION
Sato, Tsuneo,Inoue, Masami,Kobara, Satoru,Otera, Junzo,Nozaki, Hitosi
, p. 91 - 94 (1989)
Both 1,3- and 1.4-diketones are obtained from common precursors, β-methoxy-γ-phenylthio ketones.These compounds are derived through the novel phenylthio migration reaction of the aldehyde adducts with methoxy(phenylthio)-methane upon exposure to enol silyl ethers.The compounds thus obtained are converted into 1,3- and 1,4-diketones.
