Tetrahedron Letters p. 91 - 94 (1989)
Update date:2022-07-30
Sato, Tsuneo
Inoue, Masami
Kobara, Satoru
Otera, Junzo
Nozaki, Hitosi
Both 1,3- and 1.4-diketones are obtained from common precursors, β-methoxy-γ-phenylthio ketones.These compounds are derived through the novel phenylthio migration reaction of the aldehyde adducts with methoxy(phenylthio)-methane upon exposure to enol silyl ethers.The compounds thus obtained are converted into 1,3- and 1,4-diketones.
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