22094-21-9

Basic information

• Product Name: Benzeneacetaldehyde, a-(acetyloxy)-
• CAS NO: 22094-21-9
• Molecular Formula: C10H10O3
• Molecular Weight: 178.188
• Mol File: 22094-21-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzeneacetaldehyde, a-(acetyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetaldehyde, a-(acetyloxy)-(22094-21-9)
• EPA Substance Registry System: Benzeneacetaldehyde, a-(acetyloxy)-(22094-21-9)

Safety Data

• Hazardous Substances Data: 22094-21-9(Hazardous Substances Data)

Upstream product

• 119718-87-5 cyano(phenyl)methyl acetate 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 21915-53-7 2,3-epoxy-3-phenyl-1-propanol 
• 546-67-8 lead(IV) tetraacetate 
• 532-28-5 (RS)-mandelonitrile 
• 89036-99-7 Acetic acid 2-methoxy-1-phenyl-2-phenylsulfanyl-ethyl ester 
• 82027-42-7 Acetic acid ethylsulfanylcarbonyl-phenyl-methyl ester 
• 1638-63-7 2-acetoxy-2-phenylacetyl chloride 

Downstream Products

• 136022-21-4 (3E)-5-acetoxy-5-phenylpent-3-en-2-one 
• 466686-18-0 (2E)-4-acetoxy-1,4-diphenylbut-2-en-1-one 
• 34721-89-6 2-methyl-5-phenyl-furan 
• 955-83-9 2,5-diphenylfuran 
• 853-72-5 1-benzyl-2,5-diphenyl-1H-pyrrole 
• 78648-26-7 2-(1'-Hydroxybenzyl)-3-phenyl-1,3-oxazolidin 
• 78648-25-6 2-(1'-Acetoxybenzyl)-3-phenyl-1,3-oxazolidin 
• 16355-00-3 (R)-1-phenyl-1,2-ethanediol 
• 25779-13-9 (S)-1-phenyl-1,2-ethanediol 

Relevant articles and documents

Formyloxyacetoxyphenylmethane as an N-Formylating Reagent for Amines, Amino Acids, and Peptides

Formyloxyacetoxyphenylmethane is a stable, water-tolerant, N-formylating reagent for primary and secondary amines that can be used under solvent-free conditions at room temperature to prepare a range of N-formamides, N-formylanilines, N-formyl-α-amino acids, N-formylpeptides, and an isocyanide.

Highly enantioselective reaction of lithiated N-Boc-thiazolidine: A new chiral formyl anion equivalent

Reaction of lithiated N-Boc-thiazolidine 1 with various aldehydes in the presence of (-)-sparteine afforded the products with up to 93% ee. The reaction was confirmed to proceed through a dynamic thermodynamic resolution pathway. Each diastereomeric alcohol could be converted to the corresponding optically active 1,2-ethanediols.

Reduction of ethanethiol esters to aldehydes

Reduction of ethanethiol esters of α-amino acids to α-amino aldehydes by triethylsilane and catalytic palladium-on-carbon is described. α-Amino aldehydes with Boc, Cbz, or Fmoc protection could be obtained without racemization in high yield.