89499-92-3

Upstream product

• 60825-19-6 4,6-O-isopropylidene sucrose hexabenzoate 
• 100-44-7 benzyl chloride 
• 98-88-4 benzoyl chloride 
• 100-39-0 benzyl bromide 
• 71196-27-5 4,6-mono-O-isopropylidene sucrose 

Downstream Products

• 89499-93-4 2,3-di-O-benzyl-α-D-glucopyranosyl 1,3,4,6-tetra-O-benzyl-β-D-fructofuranoside 
• 364781-15-7 1',2,3,3',4',6'-hexa-O-benzyl-6-deoxy-6-iodo-sucrose 
• 364781-14-6 tetra-O-benzyl-2'-O-(4-O-allyl-2,3-di-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranosyl)-β-D-fructofuranoside 
• 364781-13-5 hepta-O-benzyl-2'-O-(6-deoxy-α-D-xylo-hex-5-enopyranosyl)-β-D-fructopyranoside 
• 76410-48-5 6-deoxy-6-fluorosucrose 
• 89499-98-9 4-O-benzoyl-2,3-di-O-benzyl-6-deoxy-6-fluoro-α-D-galactopyranosyl 1,3,4,6-tetra-O-benzyl-β-D-fructofuranoside 
• 89499-95-6 2,3-di-O-benzyl-6-deoxy-6-fluoro-4-O-mesyl-α-D-glucopyranosyl 1,3,4,6-tetra-O-benzyl-β-D-fructofuranoside 
• 89499-96-7 2,3-di-O-benzyl-6-deoxy-6-fluoro-α-D-glucopyranosyl 1,3,4,6-tetra-O-benzyl-β-D-fructofuranoside 
• 89576-83-0 2,3-di-O-benzyl-6-deoxy-6-fluoro-α-D-galactopyranosil 1,3,4,6-tetra-O-benzyl-β-D-fructofuranoside 
• 89499-94-5 2,3-di-O-benzyl-4,6-di-O-methanesulphonyl-α-D-glucopyranosyl 1,3,4,6-tetra-O-benzyl-β-D-fructofuranoside 

Relevant academic research and scientific papers

Application of the triisobutylaluminum-promoted reductive rearrangement to sucrose-5-enes

Carbohydrate-based vinyl acetals (5-hex-enopyranosides) undergo reductive rearrangement with triisobutylaluminum (TIBAL) to afford highly functionalized cyclohexanes in which both the aglycon and anomeric stereochemistry are retained. Here, we report the

The synthesis of some fluoro derivatives of sucrose.

2,3,1',3'4',6'-Hexa-O-benzylsucrose was obtained by mild acid-catalysed hydrolysis of the 4,6-O-isopropylidene derivative and then converted into its 4,6-di-O-mesyl derivative. Selective displacement of this disulphonate with fluoride anion (from tetrabut