187409-10-5

Basic information

• Product Name: Benzene, 1-chloro-3-(1,2-dibromoethyl)-
• CAS NO: 187409-10-5
• Molecular Formula: C8H7Br2Cl
• Molecular Weight: 298.405
• Mol File: 187409-10-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-3-(1,2-dibromoethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-3-(1,2-dibromoethyl)-(187409-10-5)
• EPA Substance Registry System: Benzene, 1-chloro-3-(1,2-dibromoethyl)-(187409-10-5)

Safety Data

• Hazardous Substances Data: 187409-10-5(Hazardous Substances Data)

Upstream product

• 587-04-2 m-Chlorobenzaldehyde 
• 672-65-1 (1-chloroethyl)benzene 
• 65130-47-4 3-chloro-α-bromoethylbenzene 
• 32503-27-8 tetra(n-butyl)ammonium hydrogensulfate 
• 36229-42-2 (3-chlorophenyl)magnesium bromide 
• 120121-01-9 1-(m-Chlorophenyl)ethanol 
• 620-16-6 3-chloroethylbenzene 
• 2039-85-2 3-Chlorostyrene 

Downstream Products

• 2039-85-2 3-Chlorostyrene 
• 117538-45-1 2-bromo-1-(3-chlorophenyl)ethanol 
• 217939-59-8 Propionic acid (S)-2-bromo-1-(3-chloro-phenyl)-ethyl ester 
• 194721-60-3 (S)-2-bromo-1-(3-chlorophenyl)ethyl acetate 
• 174699-77-5 (R)?2?bromo?1?(3′?chlorophenyl)ethanol 
• 115648-90-3 (S)-3-chlorostyrene oxide 
• 20697-04-5 (R)-meta-chlorostyrene oxide 
• 133220-30-1 2-[2-(3-chloro-phenyl)-oxiranylmethyl]-2-ethyl-1H-indene-1,3(2H)-dione 
• 133220-63-0 2-<2-(3-chlorophenyl)prop-2-enyl>-2-ethylindane-1,3-dione 
• 133220-70-9 3-chloro-α-(chloromethyl)-styrene 
• 157563-52-5 2-(3-chlorophenyl)prop-2-en-1-ol 
• 187409-14-9 1-(1-bromovinyl)-3-chlorobenzene 
• 89619-10-3 1-(1-bromovinyl)-4-chlorobenzene 
• 61001-11-4 2-(3-chlorophenyl)imidazo[2,1-a]isoquinoline 

Relevant articles and documents

A practical synthesis of 3-chloro-α-bromostyrene starting from 3- chloroethylbenzene

3-Chloro-α,β-dibromoethylbenzene was prepared via I2 catalyzed bromination of 3-chloro-α-bromoethylbenzene. It was dehydrobrominated with aqueous NaOH in the presence of n-Bu4N+HSO4- to give 3-chloro-

Visible-Light-Induced Regioselective C(sp3)-H Acyloxylation of Aryl-2 H-azirines with (Diacetoxy)iodobenzene

A visible-light-promoted regioselective coupling of C(sp3)-H of aryl-2H-azirine and (diacetoxy)iodobenzene has been reported. Rose Bengal as an organophotoredox catalyst has been used in this reaction. The reaction proceeds under aerobic condition at room temperature. A variety of aryl-2H-azirines gives the corresponding acyloxylated azirines under this reaction conditions. The reaction goes through a radical pathway. The protocol is also applicable on gram-scale synthesis.

Visible-Light Photoredox Catalyzed Three-Component Cyclization of 2H-Azirines, Alkynyl Bromides, and Molecular Oxygen to Oxazole Skeleton

A novel three-component cyclization of 2H-azirines, alkynyl bromides, and molecular oxygen under visible-light photoredox catalysis at room temperature has been developed, which provides a direct approach to a wide range of substituted oxazoles in moderate to good yields.