89619-19-2

Basic information

• Product Name: Benzene, 1-chloro-4-[1-[(2,2,2-trifluoroethoxy)methyl]ethenyl]-
• CAS NO: 89619-19-2
• Molecular Formula: C11H10ClF3O
• Molecular Weight: 250.648
• Mol File: 89619-19-2.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-[1-[(2,2,2-trifluoroethoxy)methyl]ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-[1-[(2,2,2-trifluoroethoxy)methyl]ethenyl]-(89619-19-2)
• EPA Substance Registry System: Benzene, 1-chloro-4-[1-[(2,2,2-trifluoroethoxy)methyl]ethenyl]-(89619-19-2)

Safety Data

• Hazardous Substances Data: 89619-19-2(Hazardous Substances Data)

Upstream product

• 75-89-8 2,2,2-trifluoroethanol 
• 89618-94-0 2-(4-chlorophenyl)prop-2-en-1-yl 4-toluenesulfonate 
• 420-87-1 sodium 2,2,2-trifluoroethanolate 
• 109125-17-9 <2-(4-chlorophenyl)prop-1-en-3-yl>trimethylammonium iodide 
• 89619-10-3 1-(1-bromovinyl)-4-chlorobenzene 
• 45941-96-6 2-(4-chlorophenyl)-3-hydroxypropene 

Relevant articles and documents

THE REACTION OF QUATERNARY AMMONIUM SALTS DERIVED FROM 2-ARYL-3-(N,N-DIMETHYLAMINO)-1-PROPENES WITH OXYGEN CONTAINING NUCLEOPHILES

A variety of quaternary ammonium salts derived from 2-aryl-3-(N,N-dimethylamino)-1-propenes have been converted to the corresponding alkyl and fluoroalkyl ethers by displacement of the ammonium group.This procedure represents an efficient means for the construction of 2-aryl substituted allylic ethers.

Effect of the α-Trifluoromethyl Moiety on the Solvolysis of Allylic Sulfonates

A series of allylic sulfonates bearing aryl substituents on the 2-position and/or trifluoromethyl groups on the 1- and/or 3-positions has been studied under solvolytic conditions in 2,2,2-trifluoroethanol.Nonarylated 1,3-di(trifluoromethyl)-substituted allylic sulfonates did not solvolyze in a conventional manner but instead gave products diagnostic of a complex isomerization-cleavage process.Mono(trifluoromethyl)-substituted allylic sulfonates solvolyzed by normal paths to give kH/kCF3 ratios of 2E6 and 4E4 for the substitution at the 1- and 3-positions, respectively.No evidence for 1,3-? interactions was discerned.